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CO chemisorption on Ir(111)

Comrie, C. M. and Weinberg, W. H. (1976) CO chemisorption on Ir(111). Journal of Vacuum Science and Technology, 13 (1). pp. 264-265. ISSN 0022-5355. http://resolver.caltech.edu/CaltechAUTHORS:20120808-074221649

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Abstract

The adsorption of carbon monoxide on the (111) crystallographic orientation of iridium both at and below room temperature has been investigated using both low‐energy electron diffraction (LEED) and thermal desorption mass spectrometry. At room temperature, CO adsorbs rapidly resulting in the appearance of a faint (√3×√3) R30° LEED pattern after only approximately 1.3×10^(−6) Torr s (1.72×10^(−4) Pa s) exposure. Upon further exposure to CO, the intensity of the overlayer LEED beams initially increases, but then decreases passing through a maximum at an exposure of approximately 2.4×10^(−6) Torr s (3.2×10^(−4) Pa s). By an exposure of 10^(−5) Torr s (1.3×10^(−3) Pa s) each of the (rather dim and diffuse) overlayer beams has split into two beams. These beams then move toward the substrate beams with increasing CO surface coverage, until near saturation coverage the angle between the split overlayer beams subtended at the (00) beam is greater than 30°.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1116/1.568864DOIUNSPECIFIED
http://avspublications.org/jvst/resource/1/jvstal/v13/i1/p264_s1PublisherUNSPECIFIED
Additional Information:© 1976 by the American Vacuum Society. Received 3 September 1975; in final form 2 October 1975. Research supported via instrumentation grants from both the National Science Foundation (Grant No. GP-37186) and the Research Corporation. Acknowledgment is also made to the Donors of the Petroleum Research Fund, administered by the American Chemical Society, for the support of this research.
Funders:
Funding AgencyGrant Number
NSFGP-37186
Research CorporationUNSPECIFIED
American Chemical Society Petroleum Research FundUNSPECIFIED
Classification Code:PACS: 82.65.M, 68.20.0, 68.43.-h, 61.05.jh, 68.49.Jk
Record Number:CaltechAUTHORS:20120808-074221649
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120808-074221649
Official Citation:Abstract: CO chemisorption on Ir(111) C. M. Comrie and W. H. Weinberg J. Vac. Sci. Technol. 13, 264 (1976); http://dx.doi.org/10.1116/1.568864
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:33001
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:08 Aug 2012 14:58
Last Modified:26 Dec 2012 15:52

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