Dervan, Peter B. and Uyehara, Tadao (1976) 7-Azabicyclo[2.2.1]heptane N-Imide as an Intermediate in the Thermal Decomposition of N-Amino-7-Azabicyclo[2.2.1]heptane and the Corresponding Benzenesulphonamide. Journal of the Chemical Society. Chemical Communications, 1976 (12). pp. 469-470. ISSN 0022-4936 http://resolver.caltech.edu/CaltechAUTHORS:20120808-075745170
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Abstract
An intermediate in the thermal decomposition of N-amino-7-azabicyclo[2.2.1]heptane and the corresponding benzenesulphonamide derivative, whose structure is consistent with the formulation 7-azabicyclo[2.2.1]heptane N-imide, affords on thermal fragmentation the hydrocarbon products hexa-1,5-diene, bicyclo[2.2.0]hexane, and cyclohexene and does not rearrange to the corresponding stable 2,3-diazabicyclo[2.2.2]oct-2-ene isomer.
| Item Type: | Article | ||||||
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| Additional Information: | © 1976 Royal Society of Chemistry. Received, 5th April 1976; Com. 359. We thank the E. I. duPont de Nemours and Co. and the National Science Foundation for support. | ||||||
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| Record Number: | CaltechAUTHORS:20120808-075745170 | ||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20120808-075745170 | ||||||
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| Official Citation: | 7-Azabicyclo[2.2.1]heptane N-imide as an intermediate in the thermal decomposition of N-amino-7-azabicyclo[2.2.1]heptane and the corresponding benzenesulphonamide Peter B. Dervan and Tadao Uyehara, J. Chem. Soc., Chem. Commun., 1976, 469 DOI: 10.1039/C39760000469 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 33003 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Ruth Sustaita | ||||||
| Deposited On: | 08 Aug 2012 15:10 | ||||||
| Last Modified: | 26 Dec 2012 15:52 |
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