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7-Azabicyclo[2.2.1]heptane N-Imide as an Intermediate in the Thermal Decomposition of N-Amino-7-Azabicyclo[2.2.1]heptane and the Corresponding Benzenesulphonamide

Dervan, Peter B. and Uyehara, Tadao (1976) 7-Azabicyclo[2.2.1]heptane N-Imide as an Intermediate in the Thermal Decomposition of N-Amino-7-Azabicyclo[2.2.1]heptane and the Corresponding Benzenesulphonamide. Journal of the Chemical Society. Chemical Communications, 1976 (12). pp. 469-470. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:20120808-075745170

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Abstract

An intermediate in the thermal decomposition of N-amino-7-azabicyclo[2.2.1]heptane and the corresponding benzenesulphonamide derivative, whose structure is consistent with the formulation 7-azabicyclo[2.2.1]heptane N-imide, affords on thermal fragmentation the hydrocarbon products hexa-1,5-diene, bicyclo[2.2.0]hexane, and cyclohexene and does not rearrange to the corresponding stable 2,3-diazabicyclo[2.2.2]oct-2-ene isomer.


Item Type:Article
Related URLs:
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http://dx.doi.org/ 10.1039/C39760000469DOIUNSPECIFIED
http://pubs.rsc.org/en/Content/ArticleLanding/1976/C3/C39760000469PublisherUNSPECIFIED
Additional Information:© 1976 Royal Society of Chemistry. Received, 5th April 1976; Com. 359. We thank the E. I. duPont de Nemours and Co. and the National Science Foundation for support.
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NSFUNSPECIFIED
E. I. duPont de Nemours and Co.UNSPECIFIED
Record Number:CaltechAUTHORS:20120808-075745170
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120808-075745170
Official Citation:7-Azabicyclo[2.2.1]heptane N-imide as an intermediate in the thermal decomposition of N-amino-7-azabicyclo[2.2.1]heptane and the corresponding benzenesulphonamide Peter B. Dervan and Tadao Uyehara, J. Chem. Soc., Chem. Commun., 1976, 469 DOI: 10.1039/C39760000469
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:33003
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:08 Aug 2012 15:10
Last Modified:26 Dec 2012 15:52

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