Kelsey, Donald R. and Bergman, Robert G. (1973) Effect of 2-Substitution on the Rearrangement of 1-Cyclopropylvinyl Cations. Journal of the Chemical Society. Chemical Communications, 16 . pp. 589-590. ISSN 0022-4936 http://resolver.caltech.edu/CaltechAUTHORS:20120808-141846921
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Abstract
2-Substitution in 1-cyclopropylvinyl cations produces a steric effect on cation generation and solvent trapping, but an electronic charge-stabilizing effect on cyclopropyl-to-cyclobutyl rearrangement.
| Item Type: | Article | ||||||||
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| Additional Information: | © 1973 Royal Society of Chemistry. Received 25th Afiril 1973; Corn. 572. We thank the National Institutes of Health, the Alfred P. Sloan Foundation, and the Camille and Henry Dreyfus Foundation for financial support. | ||||||||
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| Record Number: | CaltechAUTHORS:20120808-141846921 | ||||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20120808-141846921 | ||||||||
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| Official Citation: | Kelsey, D. R. and R. G. Bergman (1973). "Effect of 2-substitution on the rearrangement of 1-cyclopropylvinyl cations." Journal of the Chemical Society, Chemical Communications(16): 589-590. 2-Substitution in 1-cyclopropylvinyl cations produces a steric effect on cation generation and solvent trapping, but an electronic charge-stabilizing effect on cyclopropyl-to-cyclobutyl rearrangement. | ||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||
| ID Code: | 33026 | ||||||||
| Collection: | CaltechAUTHORS | ||||||||
| Deposited By: | Aucoeur Ngo | ||||||||
| Deposited On: | 08 Aug 2012 21:41 | ||||||||
| Last Modified: | 26 Dec 2012 15:53 |
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