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Effect of 2-Substitution on the Rearrangement of 1-Cyclopropylvinyl Cations

Kelsey, Donald R. and Bergman, Robert G. (1973) Effect of 2-Substitution on the Rearrangement of 1-Cyclopropylvinyl Cations. Journal of the Chemical Society. Chemical Communications, 16 . pp. 589-590. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:20120808-141846921

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Abstract

2-Substitution in 1-cyclopropylvinyl cations produces a steric effect on cation generation and solvent trapping, but an electronic charge-stabilizing effect on cyclopropyl-to-cyclobutyl rearrangement.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/C39730000589DOIUNSPECIFIED
http://pubs.rsc.org/en/content/articlelanding/1973/C3/c39730000589PublisherUNSPECIFIED
Additional Information:© 1973 Royal Society of Chemistry. Received 25th Afiril 1973; Corn. 572. We thank the National Institutes of Health, the Alfred P. Sloan Foundation, and the Camille and Henry Dreyfus Foundation for financial support.
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Funding AgencyGrant Number
NIHUNSPECIFIED
Alfred P. Sloan FoundationUNSPECIFIED
Camille and Henry Dreyfus FoundationUNSPECIFIED
Record Number:CaltechAUTHORS:20120808-141846921
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120808-141846921
Official Citation:Kelsey, D. R. and R. G. Bergman (1973). "Effect of 2-substitution on the rearrangement of 1-cyclopropylvinyl cations." Journal of the Chemical Society, Chemical Communications(16): 589-590. 2-Substitution in 1-cyclopropylvinyl cations produces a steric effect on cation generation and solvent trapping, but an electronic charge-stabilizing effect on cyclopropyl-to-cyclobutyl rearrangement.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:33026
Collection:CaltechAUTHORS
Deposited By: Aucoeur Ngo
Deposited On:08 Aug 2012 21:41
Last Modified:26 Dec 2012 15:53

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