Wrighton, Mark and Bredesen, Dale and Hammond, George S. and Gray, Harry B. (1972) Deactivation of biacetyl triplets by cyanocobaltate(III) complexes. Journal of the Chemical Society. Chemical Communications (18). pp. 1018-1019. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:20120814-131933097
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The rate of electronic energy transfer from biacetyl triplets to Co(CN)_(5)(X)^(n–)(X = CN^–, MeCN, pyridine, N_(3)^–, H_(2)O, or SCN^–) is strongly dependent on the energy of the first spin-allowed d–d transition of Co(CN)_(5)(X)^(n–), and (for X = CN^–, N_(3)^–, and SCN^–) the direct and sensitized photosubstitution yields are the same, implying a common reactive state.
|Additional Information:||© 1972 Royal Society of Chemistry. Received: 12 June 1972; Com. 999. This research was supported by the Directorate of Chemical Sciences, Air Force Office of Scientific Research, and the Army Research Office, Durham.|
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|Deposited By:||Jason Perez|
|Deposited On:||14 Aug 2012 23:17|
|Last Modified:||26 Dec 2012 15:59|
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