Wrighton, Mark and Bredesen, Dale and Hammond, George S. and Gray, Harry B. (1972) Deactivation of biacetyl triplets by cyanocobaltate(III) complexes. Journal of the Chemical Society. Chemical Communications (18). pp. 1018-1019. ISSN 0022-4936 http://resolver.caltech.edu/CaltechAUTHORS:20120814-131933097
![[img]](http://authors.library.caltech.edu/style/images/fileicons/application_pdf.png)
|
PDF
- Published Version
See Usage Policy. 199Kb |
Use this Persistent URL to link to this item: http://resolver.caltech.edu/CaltechAUTHORS:20120814-131933097
Abstract
The rate of electronic energy transfer from biacetyl triplets to Co(CN)_(5)(X)^(n–)(X = CN^–, MeCN, pyridine, N_(3)^–, H_(2)O, or SCN^–) is strongly dependent on the energy of the first spin-allowed d–d transition of Co(CN)_(5)(X)^(n–), and (for X = CN^–, N_(3)^–, and SCN^–) the direct and sensitized photosubstitution yields are the same, implying a common reactive state.
| Item Type: | Article | ||||||
|---|---|---|---|---|---|---|---|
| Additional Information: | © 1972 Royal Society of Chemistry. Received: 12 June 1972; Com. 999. This research was supported by the Directorate of Chemical Sciences, Air Force Office of Scientific Research, and the Army Research Office, Durham. | ||||||
| Funders: |
| ||||||
| Record Number: | CaltechAUTHORS:20120814-131933097 | ||||||
| Persistent URL: | http://resolver.caltech.edu/CaltechAUTHORS:20120814-131933097 | ||||||
| Related URLs: | |||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 33178 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Jason Perez | ||||||
| Deposited On: | 14 Aug 2012 23:17 | ||||||
| Last Modified: | 26 Dec 2012 15:59 |
Repository Staff Only: item control page
