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Deactivation of biacetyl triplets by cyanocobaltate(III) complexes

Wrighton, Mark and Bredesen, Dale and Hammond, George S. and Gray, Harry B. (1972) Deactivation of biacetyl triplets by cyanocobaltate(III) complexes. Journal of the Chemical Society. Chemical Communications (18). pp. 1018-1019. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:20120814-131933097

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Abstract

The rate of electronic energy transfer from biacetyl triplets to Co(CN)_(5)(X)^(n–)(X = CN^–, MeCN, pyridine, N_(3)^–, H_(2)O, or SCN^–) is strongly dependent on the energy of the first spin-allowed d–d transition of Co(CN)_(5)(X)^(n–), and (for X = CN^–, N_(3)^–, and SCN^–) the direct and sensitized photosubstitution yields are the same, implying a common reactive state.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1039/C39720001018 DOIUNSPECIFIED
http://pubs.rsc.org/en/Content/ArticleLanding/1972/C3/c39720001018PublisherUNSPECIFIED
Additional Information:© 1972 Royal Society of Chemistry. Received: 12 June 1972; Com. 999. This research was supported by the Directorate of Chemical Sciences, Air Force Office of Scientific Research, and the Army Research Office, Durham.
Funders:
Funding AgencyGrant Number
Air Force Office of Scientific Research (AFOSR) Directorate of Chemical SciencesUNSPECIFIED
Army Research Office (ARO) DurhamUNSPECIFIED
Record Number:CaltechAUTHORS:20120814-131933097
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120814-131933097
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:33178
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:14 Aug 2012 23:17
Last Modified:26 Dec 2012 15:59

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