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On the Optical Spectra of Some Transition Metal Pentacyanonitrosyl Complexes

Gray, Harry B. and Ballhausen, C. J. (1962) On the Optical Spectra of Some Transition Metal Pentacyanonitrosyl Complexes. Journal of Chemical Physics, 36 (5). pp. 1151-1153. ISSN 0021-9606. http://resolver.caltech.edu/CaltechAUTHORS:20120816-110715372

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Abstract

The visible absorption spectra of the ions [Fe(CN)_(5)NO]^(2-), [Mn(CN)_(5)NO]^(3—), and [Cr(CN)_(5)NO]^(3—) are interpreted using a crystal field level scheme of C_(4v) symmetry. Assuming a strong axial compression to be present a self‐consistent assignment is obtained for both the 3d^5 and 3d^6 electronic configurations.


Item Type:Article
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http://dx.doi.org/10.1063/1.1732707DOIUNSPECIFIED
http://link.aip.org/link/doi/10.1063/1.1732707PublisherUNSPECIFIED
Additional Information:© 1962 American Institute of Physics. Received 24 August 1961. National Science Foundation Postdoctoral Fellow, 1960-61.
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NSF Postdoctoral FellowshipUNSPECIFIED
Record Number:CaltechAUTHORS:20120816-110715372
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120816-110715372
Official Citation:On the Optical Spectra of Some Transition Metal Pentacyanonitrosyl Complexes Harry B. Gray and C. J. Ballhausen, J. Chem. Phys. 36, 1151 (1962), DOI:10.1063/1.1732707
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:33262
Collection:CaltechAUTHORS
Deposited By: Jason Perez
Deposited On:16 Aug 2012 18:53
Last Modified:26 Dec 2012 16:00

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