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The Magnetic Optical Rotation of Carbonyl Compounds

Winkler, J. (1968) The Magnetic Optical Rotation of Carbonyl Compounds. Chemical Communications (11). pp. 648-649. ISSN 1359-7345. http://resolver.caltech.edu/CaltechAUTHORS:20120829-101142708

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Abstract

Recently McCaffery et al. examined the magnetic optical activity of several ketones and stated that the n → π* transition of almost all the compounds studied showed no magnetic c.d. These results contrast with earlier measurements of magnetic o.r.d. by Shashoua and Briat, who in some of these compounds observed the presence of A terms, which are larger by a factor of 100 than the limit of sensitivity of McCaffery's apparatus. McCaffery et al. have therefore expressed doubts concerning the accuracy of Shashoua and Briat's experimental findings.


Item Type:Article
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http://dx.doi.org/10.1039/C19680000648DOIUNSPECIFIED
http://pubs.rsc.org/en/Content/ArticleLanding/1968/C1/c19680000648PublisherUNSPECIFIED
Additional Information:© 1968 Royal Society of Chemistry. Received, April 8th, 1968; Com. 435. We thank the Stiftung Volkswagenwerk for support.
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Stiftung VolkswagenwerkUNSPECIFIED
Record Number:CaltechAUTHORS:20120829-101142708
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120829-101142708
Official Citation:The magnetic optical rotation of carbonyl compounds J. Winkler Chem. Commun. (London), 1968, 648-649 DOI: 10.1039/C19680000648
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:33646
Collection:CaltechAUTHORS
Deposited By: Aucoeur Ngo
Deposited On:29 Aug 2012 17:58
Last Modified:03 Apr 2014 21:43

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