Winkler, J. (1968) The Magnetic Optical Rotation of Carbonyl Compounds. Chemical Communications (11). pp. 648-649. ISSN 1359-7345 http://resolver.caltech.edu/CaltechAUTHORS:20120829-101142708
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Recently McCaffery et al. examined the magnetic optical activity of several ketones and stated that the n → π* transition of almost all the compounds studied showed no magnetic c.d. These results contrast with earlier measurements of magnetic o.r.d. by Shashoua and Briat, who in some of these compounds observed the presence of A terms, which are larger by a factor of 100 than the limit of sensitivity of McCaffery's apparatus. McCaffery et al. have therefore expressed doubts concerning the accuracy of Shashoua and Briat's experimental findings.
|Additional Information:||© 1968 Royal Society of Chemistry. Received, April 8th, 1968; Com. 435. We thank the Stiftung Volkswagenwerk for support.|
|Official Citation:||The magnetic optical rotation of carbonyl compounds J. Winkler Chem. Commun. (London), 1968, 648-649 DOI: 10.1039/C19680000648|
|Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Aucoeur Ngo|
|Deposited On:||29 Aug 2012 17:58|
|Last Modified:||26 Dec 2012 16:04|
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