Busarow, Kerry L. and Blake, Geoffrey A. and Laughlin, K. B. and Cohen, R. C. and Lee, Y. T. and Saykally, R. J. (1987) Tunable far-infrared laser spectroscopy in a planar supersonic jet: The Σ bending vibration of Ar-H^(35)Cl. Chemical Physics Letters, 141 (4). pp. 289-291. ISSN 0009-2614. http://resolver.caltech.edu/CaltechAUTHORS:20120911-094739478
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The lowest Σ bending vibration (02°0) of Ar-H^(35)Cl has been observed near 23.6 cm^(−1) from P(23) to R(17), in a continuous planar jet expansion using a tunable far-infrared laser. A least-squares analysis has been performed to determine the centrifugal distortion constants for the ground and excited states, which will greatly facilitate the determination of an accurate intermolecular potential surface.
|Additional Information:||© 1987 Published by Elsevier B.V. Received 25 September 1987; Available online 6 December 2001. This work was supported by the Director, Office of Energy Research, Office of Basic Energy Sciences, Chemical Sciences Division of the US Department of Energy under Contract No. DE-AC03-76SF00098. The FIR laser system was funded by the National Science Foundation (Grant CHE-8612296).|
|Official Citation:||Kerry L. Busarow, Geoffrey A. Blake, K.B. Laughlin, R.C. Cohen, Y.T. Lee, R.J. Saykally, Tunable far-infrared laser spectroscopy in a planar supersonic jet: The Σ bending vibration of Ar-H35Cl, Chemical Physics Letters, Volume 141, Issue 4, 13 November 1987, Pages 289-291, ISSN 0009-2614, 10.1016/0009-2614(87)85025-X.|
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|Deposited By:||Tony Diaz|
|Deposited On:||11 Sep 2012 18:58|
|Last Modified:||11 Sep 2012 18:58|
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