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On chemical activation by collisions

Tolman, Richard C. and Yost, Don M. and Dickinson, Roscoe G. (1927) On chemical activation by collisions. Proceedings of the National Academy of Sciences of the United States of America, 13 (4). pp. 188-192. ISSN 0027-8424. http://resolver.caltech.edu/CaltechAUTHORS:TOLpnas27

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Abstract

In the case of first order unimolecular gas reactions, such as the decomposition of nitrogen pentoxide, there is a well-known, theoretical difficulty (1) in discovering any process of activation rapid enough to maintain the full Maxwell-Boltzmann quota of activated molecules and thus to assure a first order course to the reaction. This problem has recently been treated anew by Fowler and Rideal,(2) who consider, in a somewhat new light, the possibility of activation by molecular collisions.


Item Type:Article
Additional Information:Copyright © 1927 by the National Academy of Sciences. Communicated March 3, 1927.
Record Number:CaltechAUTHORS:TOLpnas27
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:TOLpnas27
Alternative URL:http://www.pnas.org/content/vol13/issue4/
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:3405
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:05 Jun 2006
Last Modified:14 Nov 2014 19:19

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