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Molecular Interactions and Hydrogen Bond Tunneling Dynamics: Some New Perspectives

Saykally, Richard J. and Blake, Geoffrey A. (1993) Molecular Interactions and Hydrogen Bond Tunneling Dynamics: Some New Perspectives. Science, 259 (5101). pp. 1570-1575. ISSN 0036-8075. http://resolver.caltech.edu/CaltechAUTHORS:20120919-101541968

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Abstract

The recent development of tunable far-infrared lasers and other high-resolution spectroscopic probes of weakly bound clusters is having a significant impact on our understanding of intermolecular forces and on the complex quantum tunneling dynamics that occur in hydrogen-bonded systems. Far-infrared studies of a variety of interactions are discussed, including several prototypical water-hydrophobe complexes, the water trimer, and the ammonia dimer. Particular attention is paid to the inversion of spectroscopic data to yield detailed intermolecular potential energy surfaces. Investigations of nonpairwise additivity are also described.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1126/science.259.5101.1570DOIUNSPECIFIED
http://www.sciencemag.org/content/259/5101/1570PublisherUNSPECIFIED
http://www.jstor.org/stable/2880658OtherUNSPECIFIED
Additional Information:© 1993 American Association for the Advancement of Science. We thank the many graduate students and postdoctoral fellows at Berkeley and Caltech whose efforts made this research possible. The FIRVRTS program at Berkeley is supported by NSF grant CHE-9123335, and at Caltech by NSF grant CHE-8957228. G.A.B. also acknowledges support from the David and Lucille Packard and Alfred P. Sloan Foundations.
Funders:
Funding AgencyGrant Number
NSFCHE-9123335
NSFCHE-8957228
David and Lucille Packard FoundationUNSPECIFIED
Alfred P. Sloan FoundationUNSPECIFIED
Record Number:CaltechAUTHORS:20120919-101541968
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20120919-101541968
Official Citation:Molecular Interactions and Hydrogen Bond Tunneling Dynamics: Some New Perspectives Richard J. Saykally and Geoffrey A. Blake Science , New Series, Vol. 259, No. 5101 (Mar. 12, 1993), pp. 1570-1575
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:34205
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:19 Sep 2012 17:47
Last Modified:19 Sep 2012 17:47

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