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Atmospheric argon contamination of ocean island basalt olivine phenocrysts

Farley, K. A. and Craig, H. (1994) Atmospheric argon contamination of ocean island basalt olivine phenocrysts. Geochimica et Cosmochimica Acta, 58 (11). pp. 2509-2517. ISSN 0016-7037. http://resolver.caltech.edu/CaltechAUTHORS:20121113-105804078

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Abstract

^(40)Ar/^(36)Ar and helium and argon concentrations have been repeatedly measured on olivine phenocrysts in a single tholeiitic basalt (PIN-12) from the Juan Fernandez hotspot. Forty olivine splits were analyzed by crushing of bulk samples or laser fusion of single crystals. The measured ^(40)Ar/^(36)Ar ratios span a very large range (400–7700) and are consistent with binary mixing of two argon components. Unlike argon, helium in repeated measurements of this single basalt flow has a reproducible isotopic ratio, 17 times the air ^3He/^4He value. It is unlikely that such large variations in ^(40)Ar/^(36)Ar represent microscale mantle heterogeneity. Rather the results indicate highly variable mixing proportions of a mantle-derived radiogenic argon component (^(40)Ar/^(36)Ar > 7700) and an isotopically air-like endmember that is almost certainly an atmospheric contaminant. This air-like constituent cannot be removed by physical and chemical treatments of the olivines. Analysis of individual crystals by laser fusion shows that both the radiogenic and the contaminant components are in fluid inclusions. Siting of the contaminant in inclusions requires the addition of airderived noble gases to hotspot magmas prior to or during emplacement, a process that may occur by assimilation of altered crust during crustal storage or, alternatively, by direct addition of air or seawater to the magma. In either case the olivines must continue to trap argon, presumably by fracture annealing and/or bubble enclosure, after the contaminating event. If atmospheric contamination is a general phenomenon, the ^(40)Ar/^(36)Ar composition of olivines (and possibly of basalt glasses as well) must be only a lower limit for the mantle source ratio. With the exception of helium, the other noble gases may be similarly compromised. Our results support contentions that lavas with near-atmospheric noble gas compositions reflect severe atmospheric contamination, rather than the air-like signature of an undegassed primitive mantle reservoir.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1016/0016-7037(94)90027-2DOIUNSPECIFIED
http://www.sciencedirect.com/science/article/pii/0016703794900272PublisherUNSPECIFIED
Additional Information:© 1994 Elsevier Science Ltd. Received September 7, 1993; accepted in revised form February 1, 1994. We thank R. Comer and V. Craig for their assistance in the field-work on the Juan Fernandez Isiands. We are grateful to Drs. G. B. Dalrymple, M. Harrison, and M. Heizler for their generosity in making the laser-fusion measurements and for discussions of the methodology. K. Turekian and D. Graham made many helpful suggestions in reviewing the manuscript. This work was supported by National Science Foundation Grants OCE-8720740 and EAR-88 16945 to the Isotope Laboratory, Scripps Institution of Oceanography. Editorial handling: K. Marti
Funders:
Funding AgencyGrant Number
NSFOCE-8720740
NSFEAR-8816945
Record Number:CaltechAUTHORS:20121113-105804078
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20121113-105804078
Official Citation:K.A. Parley, H. Craig, Atmospheric argon contamination of ocean island basalt olivine phenocrysts, Geochimica et Cosmochimica Acta, Volume 58, Issue 11, June 1994, Pages 2509-2517, ISSN 0016-7037, 10.1016/0016-7037(94)90027-2. (http://www.sciencedirect.com/science/article/pii/0016703794900272)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:35425
Collection:CaltechAUTHORS
Deposited By: Ruth Sustaita
Deposited On:13 Nov 2012 19:15
Last Modified:13 Nov 2012 19:15

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