Pearson, D. H. and Ahn, C. C. and Fultz, B. (1993) White lines and d-electron occupancies for the 3d and 4d transition metals. Physical Review B, 47 (14). pp. 8471-8478. ISSN 0163-1829 http://resolver.caltech.edu/CaltechAUTHORS:PEAprb93
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We used electron-energy-loss spectrometry to measure the intensities of the white lines found at the onsets of the L2 and L3 absorption edges for most of the 3d and 4d transition metals. The intensities of the white lines, normalized to the trailing background, decreased nearly linearly with increasing atomic number, reflecting the filling of the d states. One-electron Hartree-Slater calculations of the white-line intensities were in good agreement with observed spectra. Empirical correlations between normalized white-line intensity and d-state occupancy provide a method for measuring changes in d-state occupancy due to alloying.
|Additional Information:||©1993 The American Physical Society. Received 27 July 1992; revised manuscript received 30 November 1992. We thank Dr. Peter Rez of Arizona State University for useful discussions. This work was supported by the United States Department of Energy under Contract No. DE-FG03-86ER45270. The TEM facility was supported by the National Science Foundation under Grant No. DMR-8811795. The Gatan 666 EELS spectrometer was acquired through an equipment grant from Caltech's Program in Advanced Technologies, supported by Aerojet General, General Motors, and TRW.|
|Subject Keywords:||X-RAY-ABSORPTION; IONIZATION CROSS-SECTIONS; ENERGY-LOSS; BAND THEORY; SPECTRA; STATES; SHELL; SPECTROSCOPY; COLLISIONS; PLATINUM|
|Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Tony Diaz|
|Deposited On:||29 Jun 2006|
|Last Modified:||26 Dec 2012 08:55|
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