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Thermodynamic study of the 4He monolayer adsorbed on Grafoil

Elgin, Robert L. and Goodstein, David L. (1974) Thermodynamic study of the 4He monolayer adsorbed on Grafoil. Physical Review A, 9 (6). pp. 2657-2675. ISSN 0556-2791. http://resolver.caltech.edu/CaltechAUTHORS:ELGpra74

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Abstract

A calorimetric and vapor-pressure study of the behavior of 4He adsorbed on Grafoil in the temperature range 4 to 15 K is reported. These results have been combined with preexisting low-temperature heat-capacity data to form a complete thermodynamic description of the film. The Grafoil substrate evidently consists almost entirely of basal-plane graphite, with only a small fraction of energetically distinct adsorption sites. Techniques of semiempirical modelling are introduced which make it possible to eliminate the effects both of these inhomogeneities and of the formation of second and higher layers, so that a detailed picture may be formed of the behavior of the 4He first layer on an ideal graphite substrate. The binding energy of a 4He atom on the graphite substrate is reported to be 143 ± 2 K, with a first excited state at 89 ± 3 K. A lattice-gas ordering transition occurs near 3 K at a coverage corresponding to one 4He atom for every three carbon hexagons in the graphite surface, and is used as a fiducial for calibrating our system relative to those of previous investigators. At both higher and lower densities the film seems little influenced by the crystal structure of the substrate. Particular attention is given to the high-coverage low-temperature region, which has been identified as a two-dimensional (2D) solid bounded by a melting-phase transition. The available data are combined with two-dimensional elastic theory to establish the presence of low-lying transverse sound modes, thus confirming the solidlike character of this medium. The behavior of the thermodynamic variables of state through the observed transition is also presented. The theoretical implications of the existence of a 2D solid are discussed, together with a dislocation theory of melting which gives rise to the well-known three-dimensional Lindemann empirical melting formula without an adjustable parameter. It is shown that at very low coverage the film does not form a low-density solid as previously suggested, but is rather dominated by substrate inhomogeneities. At intermediate temperatures and coverages the film is a fluid which is accurately described if a leading-order quantum virial correction is made to the 2D ideal-gas equation of state.


Item Type:Article
Additional Information:©1974 The American Physical Society Received 17 December 1973 The authors owe a substantial debt of gratitude to Professor R. P. Feynman, not only for the very real, direct contributions he has made to this work, but also for his continuing enthusiasm and support. We are also indebted to Professor J. G. Dash, the other members of BDHMV, and the rest of the Seattle group for their generous sharing of data and ideas. Professor G. A. Stewart has materially aided the progress of this work, and we are grateful to him and to Jeffrey Greif for countless discussions and contributions. [R.L.E. was] supported in part under NSF Grant No. GH34682.
Record Number:CaltechAUTHORS:ELGpra74
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:ELGpra74
Alternative URL:http://dx.doi.org/10.1103/PhysRevA.9.2657
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:4796
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:07 Sep 2006
Last Modified:26 Dec 2012 09:01

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