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Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes

Hu, Xile and Cossairt, Brandi M. and Brunschwig, Bruce S. and Lewis, Nathan S. and Peters, Jonas C. (2005) Electrocatalytic hydrogen evolution by cobalt difluoroboryl-diglyoximate complexes. Chemical Communications, 2005 (37). pp. 4723-4725. ISSN 1359-7345. http://resolver.caltech.edu/CaltechAUTHORS:HUXcc05

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Abstract

In the presence of moderately strong acids in CH3CN, cobalt complexes with BF2-bridged diglyoxime ligands are active catalysts for the reduction of protons to H2 at potentials as positive as –0.28 V vs. SCE.


Item Type:Article
Additional Information:© Royal Society of Chemistry 2005 Received (in Berkeley, CA, USA) 28th June 2005, Accepted 29th July 2005. First published on the web 23rd August 2005 For financial support we acknowledge the NSF through a Chemical Bonding Center (CBC). We also thank Prof. Alex Sessions for his generous help with the gas chromatography experiments.
Record Number:CaltechAUTHORS:HUXcc05
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:HUXcc05
Alternative URL:http://dx.doi.org/10.1039/b509188h
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:4825
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:08 Sep 2006
Last Modified:26 Dec 2012 09:01

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