Goddard, William A., III (1968) Concerning the stability of the negative ions H and Li. Physical Review, 172 (1). pp. 712. ISSN 0031899X. http://resolver.caltech.edu/CaltechAUTHORS:GODDpr68b

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Abstract
The unrestricted HartreeFock (UHF) wave functions for H and for Li have the Z+1th electron at infinity, and thus have the same energy as the neutral atoms. That is, the stability of these negative ions is not accounted for by Slater determinant wave functions, not even if the orbitals are allowed to split. We show that the difficulty here is that the UHF wave functions do not have the proper spin symmetry. If the Slater determinant is spinprojected and the orbitals optimized after projection (to obtain what is called the GF wave function), these negative ions are predicted correctly to be stable. Since the GF wave function leads to an independent particle interpretation, we see that instantaneous polarization of the neutralatom orbitals by the Z+1th electron is not crucial to the stability of these negative ions. From an analysis of the differences between the UHF and GF wave functions, we find that the key term leading to stability of the negative ions is an exchange term (particularly the nuclear attraction part of this term), just like the exchange term important in the valencebond wave function of H2.
Item Type:  Article 

Additional Information:  ©1968 The American Physical Society. Received 8 January 1968. I thank John Armstrong and Len Doberne for some assistance with the calculations. This research was partially supported by a grant (GP6965) from the National Science Foundation. 
Record Number:  CaltechAUTHORS:GODDpr68b 
Persistent URL:  http://resolver.caltech.edu/CaltechAUTHORS:GODDpr68b 
Alternative URL:  http://dx.doi.org/10.1103/PhysRev.172.7 
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ID Code:  5212 
Collection:  CaltechAUTHORS 
Deposited By:  Tony Diaz 
Deposited On:  05 Oct 2006 
Last Modified:  26 Dec 2012 09:04 
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