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Aluminophosphate molecular sieves comprised of hydrated triple crankshaft chains

Li, Hong-Xin and Davis, Mark E. and Higgins, John B. and Dessau, Ralph M. (1993) Aluminophosphate molecular sieves comprised of hydrated triple crankshaft chains. Journal of the Chemical Society. Chemical Communications, 1993 (4). pp. 403-405. ISSN 0022-4936. http://resolver.caltech.edu/CaltechAUTHORS:LIHjcscc93

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Abstract

We report the first synthesis of pure aluminophosphate hydrate H2 (AlPO4-H2) and its structure; AlPO4-H2 is constructed exclusively from a hydrated chain building unit that also builds the 18-ring VPI-5 structure and has one-dimensional channels circumscribed by highly elliptical rings consisting often oxygen atoms, implications from the existence of this building unit for the synthesis of novel aluminophosphate molecular sieves and for the synthesis of aluminosilicate and silicate analogues of AlPO4-H2 and VPI-5 are discussed.


Item Type:Article
Additional Information:© Royal Society of Chemistry 1993 Received, 23rd October 1992; Corn. 210.56670 Support of this work was provided by the NSF Alan T. Waterman Award to M.E.D. H.X.L. thanks Akzo America, Inc. for financial support. The synchrotron X-ray data were collected at X7A beam line, National Synchrotron Light Source, Brookhaven National Laboratory, which is supported by the US Department of Energy, Division of Material Science and Division of Chemical Science.
Record Number:CaltechAUTHORS:LIHjcscc93
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:LIHjcscc93
Alternative URL:http://dx.doi.org/10.1039/C39930000403
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:5399
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:16 Oct 2006
Last Modified:26 Dec 2012 09:05

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