Houston, William V. (1927) A spectroscopic determination of e/m. Physical Review, 30 (5). pp. 608-613. ISSN 0031-899X. http://resolver.caltech.edu/CaltechAUTHORS:HOUpr27b
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Rydberg constants for hydrogen and helium.—By an interferometer method the wave-lengths of the hydrogen lines at 6563A and 4861A were measured with reference to λ5015.6750 of He as standard. The values so obtained were, for the doublet at 6563A, 6562.7110±.0018 and 6562.8473±.0009; and for the doublet at 4861, 4861.2800±.0013 and 4861.3578±0022. Similarly the wave-lengths of the 4686 lines of ionized helium were found to be 4685.7030±.0012 and 4685.8030±.0026. From these values of the wave-lengths the Rydberg constant for hydrogen, RH is calculated to be 109,677.759±.008, and the Rydberg constant for helium, RHe, to be 109, 722.403±.004. Calculation of e/m.—The ratio of the mass of the electron to the mass of the hydrogen nucleus, m/mH, is given by m/mH=(RHe-RH)(mHe-m)/RH(mHe-mH)=1.33648(RHe-RH)/RH. The value of e/m is given in terms of the Faraday constant as e/m=(mH/m)(F/mH). If the values of RH and RHe calculated above be substituted in these expressions and if it be assumed that F=96470 abamp. per gr. mol. and mH=1.0072, it is found that e/m has the value (1.7606±.0010)×10^(7) e.m.u. per gr.
|Additional Information:||©1927 The American Physical Society. Received 29 July 1927. [W.V.H. was a] National Research Fellow in Physics.|
|Usage Policy:||No commercial reproduction, distribution, display or performance rights in this work are provided.|
|Deposited By:||Tony Diaz|
|Deposited On:||27 Oct 2006|
|Last Modified:||26 Dec 2012 09:14|
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