Vibrationally resolved partial cross sections and asymmetry parameters for carbon K-shell photoionization of the CO2 molecule

Abstract

We have measured the vibrationally resolved partial cross sections \sigma_{v_1^{\prime}} and asymmetry parameters \beta_{v_1^{\prime}} for C K-shell photoionization of the CO2 molecule in the Σu shape resonance region above the C K-shell ionization threshold. The positions of both the maxima of \sigma_{v_1^{\prime}} and the minima of \beta_{v_1^{\prime}} move towards the C K-shell threshold with increasing symmetric stretching vibrational excitation v'1 in the C 1s single-hole state. Calculations employing the relaxed-core Hartree–Fock approach reproduce the observed vibrational effects.