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Hollisterite (Al_3Fe), kryachkoite (Al,Cu)_6(Fe,Cu), and stolperite (AlCu): Three new minerals from the Khatyrka CV3 carbonaceous chondrite

Ma, Chi and Lin, Chaney and Bindi, Luca and Steinhardt, Paul J. (2017) Hollisterite (Al_3Fe), kryachkoite (Al,Cu)_6(Fe,Cu), and stolperite (AlCu): Three new minerals from the Khatyrka CV3 carbonaceous chondrite. American Mineralogist, 102 (3). pp. 690-693. ISSN 0003-004X. http://resolver.caltech.edu/CaltechAUTHORS:20170306-173459557

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Abstract

Our nanomineralogy investigation of the Khatyrka CV3 carbonaceous chondrite has revealed three new alloy minerals—hollisterite (IMA 2016-034; Al_3Fe), kryachkoite [IMA 2016-062; (Al,Cu)_6(Fe,Cu)], and stolperite (IMA 2016-033; AlCu)—in section 126A of USNM 7908. Hollisterite occurs only as one crystal with stolperite, icosahedrite, and khatyrkite, showing an empirical formula of Al_(2.89)Fe_(0.77)Cu_(0.32)Si_(0.02) and a monoclinic C2/m structure with a = 15.60 Å, b = 7.94 Å, c = 12.51 Å, b = 108.1°, V = 1472.9 Å^3, Z = 24. Kryachkoite occurs with khatyrkite and aluminum, having an empirical formula of Al5.45Cu0.97Fe0.55Cr0.02Si0.01 and an orthorhombic Cmc21 structure with a = 7.460 Å, b = 6.434 Å, c = 8.777 Å, V = 421.3 Å^3, Z = 4. Stolperite occurs within khatyrkite, or along with icosahedrite and/or hollisterite and khatyrkite, having an empirical formula of Al_(1.15)Cu_(0.81)Fe_(0.04) and a cubic Embedded Image structure with a = 2.9 Å, V = 24.4 Å^3, Z = 1. Specific features of the three new minerals, and their relationships with the meteorite matrix material, add significant new evidence for the extraterrestrial origin of the Al-Cu-Fe metal phases in the Khatyrka meteorite. Hollisterite is named in honor of Lincoln S. Hollister at Princeton University for his extraordinary contributions to earth science. Kryachkoite is named in honor of Valery Kryachko who discovered the original samples of the Khatyrka meteorite in 1979. Stolperite is named in honor of Edward M. Stolper at California Institute of Technology for his fundamental contributions to petrology and meteorite research.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.2138/am-2017-5991DOIArticle
http://ammin.geoscienceworld.org/content/102/3/690PublisherArticle
Additional Information:© 2017 Mineralogical Society of America. Manuscript received October 21, 2016. Manuscript accepted November 12, 2016. Manuscript handled by Ian Swainson. SEM, EBSD, and EPMA were carried out at the Caltech GPS Analytical Facility, which is supported, in part, by NSF grants NSF EAR-0318518 and DMR-0080065. We thank Laurence Garvie, Alan Rubin, and Makoto Kimura for their constructive reviews.
Funders:
Funding AgencyGrant Number
NSFEAR-0318518
NSFDMR-0080065
Subject Keywords:Hollisterite, Al_3Fe, kryachkoite, (Al,Cu)_6(Fe,Cu), stolperite, AlCu, new minerals, Khatyrka, carbonaceous chondrite, meteorite
Record Number:CaltechAUTHORS:20170306-173459557
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20170306-173459557
Official Citation:Hollisterite (Al3Fe), kryachkoite (Al,Cu)6(Fe,Cu), and stolperite (AlCu): Three new minerals from the Khatyrka CV3 carbonaceous chondrite Chi Ma, Chaney Lin, Luca Bindi, Paul J. Steinhardt American Mineralogist Mar 2017, 102 (3) 690-693; DOI: 10.2138/am-2017-5991
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:74823
Collection:CaltechAUTHORS
Deposited By: Kristin Buxton
Deposited On:07 Mar 2017 05:56
Last Modified:07 Mar 2017 05:56

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