Dorman, Douglas E. and Angyal, S. J. and Roberts, J. D. (1969) Nuclear magnetic resonance spectroscopy: 13C spectra of unsubstituted inositols. Proceedings of the National Academy of Sciences of the United States of America, 63 (3). pp. 612-614. ISSN 0027-8424 http://resolver.caltech.edu/CaltechAUTHORS:DORpnas69
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The chemical shifts of 13C in natural abundance have been obtained from nuclear magnetic resonance spectra of scyllo-, myo-,chiro-, and epi-inositols at 15.1 MHz. A set of empirical substituent parameters were derived and shown to be moderately successful in correlating the 13C resonance-line positions for these substances. The substituent parameters conform generally to the idea that steric hindrance or proximity effects are of special importance in influencing chemical shifts of carbons in cyclohexane systems.
|Additional Information:||© 1969 by the National Academy of Sciences. Communicated May 5, 1969. Supported by the U.S. Public Health Service, research grant GM-11072-07 from the Division of General Medical Sciences. Contribution No. 3854, Gates and Crellin Laboratories of Chemistry, California Institute of Technology, Pasadena.|
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|Deposited By:||Tony Diaz|
|Deposited On:||12 Mar 2007|
|Last Modified:||26 Dec 2012 09:33|
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