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Subsurface oxide plays a critical role in CO_2 activation by Cu(111) surfaces to form chemisorbed CO_2 , the first step in reduction of CO_2

Favaro, Marco and Xiao, Hai and Cheng, Tao and Goddard, William A. and Yano, Junko and Crumlin, Ethan J. (2017) Subsurface oxide plays a critical role in CO_2 activation by Cu(111) surfaces to form chemisorbed CO_2 , the first step in reduction of CO_2. Proceedings of the National Academy of Sciences of the United States of America, 114 (26). pp. 6706-6711. ISSN 0027-8424. PMCID PMC5495248. http://resolver.caltech.edu/CaltechAUTHORS:20170613-075002945

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Abstract

A national priority is to convert CO_2 into high-value chemical products such as liquid fuels. Because current electrocatalysts are not adequate, we aim to discover new catalysts by obtaining a detailed understanding of the initial steps of CO_2 electroreduction on copper surfaces, the best current catalysts. Using ambient pressure X-ray photoelectron spectroscopy interpreted with quantum mechanical prediction of the structures and free energies, we show that the presence of a thin suboxide structure below the copper surface is essential to bind the CO_2 in the physisorbed configuration at 298 K, and we show that this suboxide is essential for converting to the chemisorbed CO_2 in the presence of water as the first step toward CO_2 reduction products such as formate and CO. This optimum suboxide leads to both neutral and charged Cu surface sites, providing fresh insights into how to design improved carbon dioxide reduction catalysts.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://dx.doi.org/10.1073/pnas.1701405114 DOIArticle
http://www.pnas.org/content/114/26/6706PublisherArticle
http://www.pnas.org/lookup/suppl/doi:10.1073/pnas.1701405114/-/DCSupplementalPublisherSupporting Information
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC5495248/PubMed CentralArticle
ORCID:
AuthorORCID
Xiao, Hai0000-0002-5880-8649
Cheng, Tao0000-0003-4830-177X
Goddard, William A.0000-0003-0097-5716
Yano, Junko0000-0001-6308-9071
Additional Information:© 2017 National Academy of Sciences. Freely available online through the PNAS open access option. Contributed by William A. Goddard III, May 9, 2017 (sent for review January 26, 2017; reviewed by Charles T. Campbell and Bruce E. Koel). This work was supported through the Office of Science, Office of Basic Energy Science (BES), of the US Department of Energy (DOE) under Award DE-SC0004993 to the Joint Center for Artificial Photosynthesis and as part of the Joint Center for Energy Storage Research, DOE Energy Innovation Hubs. The Advanced Light Source is supported by the Director, Office of Science, Office of BES, of the US DOE under Contract DE-AC02-05CH11231. The QM calculations were carried out on the Zwicky supercomputer at Caltech. M.F. and H.X. contributed equally to this work. Author contributions: M.F., H.X., T.C., W.A.G., J.Y., and E.J.C. designed research, performed research, analyzed data, and wrote the paper. Reviewers: C.T.C., University of Washington; and B.E.K., Princeton University. The authors declare no conflict of interest. This article contains Supporting Information online at www.pnas.org/lookup/suppl/doi:10.1073/pnas.1701405114/-/DCSupplemental.
Group:JCAP
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-SC0004993
Department of Energy (DOE)DE-AC02-05CH11231
CaltechUNSPECIFIED
Subject Keywords:CO_2 reduction; suboxide copper; ambient pressure XPS; density functional theory; M06L
PubMed Central ID:PMC5495248
Record Number:CaltechAUTHORS:20170613-075002945
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:20170613-075002945
Official Citation:Marco Favaro, Hai Xiao, Tao Cheng, William A. Goddard III, Junko Yano, and Ethan J. Crumlin Subsurface oxide plays a critical role in CO2 activation by Cu(111) surfaces to form chemisorbed CO2, the first step in reduction of CO2 PNAS 2017 114 (26) 6706-6711; published ahead of print June 12, 2017, doi:10.1073/pnas.1701405114
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:78138
Collection:CaltechAUTHORS
Deposited By: Donna Wrublewski
Deposited On:13 Jun 2017 16:01
Last Modified:17 Jul 2017 21:38

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