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Theory of the specific heat of electrolytes

Zwicky, F. (1926) Theory of the specific heat of electrolytes. Proceedings of the National Academy of Sciences of the United States of America, 12 (2). pp. 86-92. ISSN 0027-8424. http://resolver.caltech.edu/CaltechAUTHORS:ZWIpnas26a

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Abstract

No molecular theory of the specific heat of liquids has been deduced till now. The considerations given in this paper may be regarded as a first attempt to solve that problem. Most molecular theories of solutions regard the solvent as a continuum, treating only the solute as composed of molecules. In this theory this simplification is made wherever possible. For the treatment of certain phenomena, however, it is too great an idealization, and it is necessary to consider the molecular character of the solvent also. As in the theories of other properties of solutions, only differences between the specific heat of the solution and the pure solvent are calculated. The application of the principles to be deduced, to any dilute solution or liquid mixture does not seem to offer any serious difficulties. It seems possible, that by proceeding logically in this direction we may find the key to the explanation of the specific heat of liquids on the basis of molecular models.


Item Type:Article
Additional Information:© 1926 by the National Academy of Sciences. Communicated January 4, 1926. In the present paper we give a general outline of the considerations underlying our theory and some of the results. A detailed account of the intermediate mathematical steps will be published in another place. [F.Z. was an] International Research Fellow in Physics.
Record Number:CaltechAUTHORS:ZWIpnas26a
Persistent URL:http://resolver.caltech.edu/CaltechAUTHORS:ZWIpnas26a
Alternative URL:http://www.pnas.org/cgi/reprint/12/2/86
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:8821
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:20 Sep 2007
Last Modified:26 Dec 2012 09:42

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