creators_name: Nakayama, Keisuke creators_name: Tanabe, Katsuaki creators_name: Atwater, Harry A. creators_id: Nakayama-K creators_id: Tanabe-K creators_id: Atwater-H-A type: article datestamp: 2008-09-29 23:29:42 lastmod: 2008-09-29 23:29:42 metadata_visibility: show title: Plasmonic nanoparticle enhanced light absorption in GaAs solar cells ispublished: pub subjects: cls full_text_status: public keywords: current density, gallium arsenide, III-V semiconductors, nanoparticles, nanotechnology, short-circuit currents, solar cells, surface plasmons, surface resistance note: ©2008 American Institute of Physics. Received 24 July 2008; accepted 31 August 2008; published 22 September 2008. This work was supported by the Department of Energy, Basic Energy Sciences under Grant No. DE-FG02-07ER46405, and Nippon Oil Corporation. We also acknowledge support from the Center for Science and Engineering of Materials (CSEM), a NSF Material Research Science and Engineering Center at Caltech, for facilities use. abstract: We demonstrate an improvement in efficiency of optically thin GaAs solar cells decorated with size-controlled Ag nanoparticles fabricated by masked deposition through anodic aluminum oxide templates. The strong scattering by the interacting surface plasmons in densely formed high aspect-ratio nanoparticles effectively increases the optical path of the incident light in the absorber layers resulting in an 8% increase in the short circuit current density of the cell. The nanoparticle array sheet conductivity also reduces the cell surface sheet resistance evidenced by an improved fill factor. This dual function of plasmonic nanoparticles has potential to enable thinner photovoltaic layers in solar cells. date: 2008-09-22 date_type: published publication: Applied Physics Letters volume: 93 number: 12 publisher: American Institute of Physics pagerange: Art. No. 121904 id_number: CaltechAUTHORS:NAKapl08 refereed: TRUE issn: 0003-6951 official_url: http://resolver.caltech.edu/CaltechAUTHORS:NAKapl08 related_url_url: http://dx.doi.org/10.1063/1.2988288 related_url_url: http://link.aip.org/link/?APPLAB/93/121904/1 related_url_type: doi related_url_type: pub referencetext: 1. H. R. Stuart and D. G. Hall, Appl. Phys. Lett. 69, 2327 (1996). 2. H. R. Stuart and D. G. Hall, Appl. Phys. Lett. 73, 3815 (1998). 3. D. M. Schaadt, B. Feng, and E. T. Yu, Appl. Phys. Lett. 86, 063106 (2005). 4. S. Pillai, K. R. Catchpole, T. Trupke, and M. A. Green, J. Appl. Phys. 101, 093105 (2007). 5. B. P. Rand, P. Peumans, and S. R. Forrest, J. Appl. Phys. 96, 7519 (2004). 6. C. F. Bohren and D. R. Huffman, Absorption and Scattering of Light by Small Particles (Wiley, New York, 1983). 7. H. Masuda and M. Satoh, Jpn. J. Appl. Phys., Part 2 35, L126 (1996). 8. K. Tanabe, K. Nakayama, and H. A. Atwater (unpublished). 9. K. Nakayama, K. Tanabe, and H. A. Atwater, Proc. SPIE 7047, 704708 (2008). 10. S. Ono, M. Saito, and H. Asoh, Electrochim. Acta 51, 827 (2005). 11. P. Royer, J. P. Goudonnet, R. J. Warmack, and T. L. Ferrell, Phys. Rev. B 35, 3753 (1987). 12. G. Fuster, J. M. Tyler, N. E. Brener, J. Callaway, and D. Bagayoko, Phys. Rev. B 42, 7322 (1990). 13. J. S. Biteen, N. S. Lewis, and H. A. Atwater, Appl. Phys. Lett. 88, 131109 (2006). 14. S. A. Maier and H. A. Atwater, J. Appl. Phys. 98, 011101 (2005). 15. S. P. Tobin, S. M. Vernon, C. Bajgar, L. M. Geoffroy, C. J. Keavney, M. M. Sanfacon, and V. E. Haven, Sol. Cells 24, 103 (1988). 16. D. E. Aspnes, S. M. Keiso, R. A. Logan, and R. Bhat, J. Appl. Phys. 60, 754 (1986). 17. J.-H. Kim, D. H. Lim, and G. M. Yang, J. Vac. Sci. Technol. B 16, 558 (1998). citation: Nakayama, Keisuke and Tanabe, Katsuaki and Atwater, Harry A. (2008) Plasmonic nanoparticle enhanced light absorption in GaAs solar cells. Applied Physics Letters, 93 (12). Art. No. 121904. ISSN 0003-6951 http://resolver.caltech.edu/CaltechAUTHORS:NAKapl08 document_url: http://authors.library.caltech.edu/11799/1/NAKapl08.pdf