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Deconstructive Functionalization of Ketones via an LMCT-Promoted C–C Cleavage

Xu, Yan and Dong, Guangbin (2020) Deconstructive Functionalization of Ketones via an LMCT-Promoted C–C Cleavage. Chem, 6 (1). pp. 10-11. ISSN 2451-9294. https://resolver.caltech.edu/CaltechAUTHORS:20200109-110921859

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Abstract

In this issue of Chem, Zuo and coworkers report an exciting new strategy for the deconstructive functionalization of ketones. Through merging Lewis-acid-catalyzed nucleophilic 1,2-addition and ligand-to-metal charge transfer (LMCT)-promoted C–C cleavage, common strained and unstrained ketones are transformed into synthetically valuable scaffolds with high efficiency under mild conditions.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1016/j.chempr.2019.12.013DOIArticle
ORCID:
AuthorORCID
Xu, Yan0000-0003-2808-7964
Additional Information:© 2019 Elsevier Inc. Available online 9 January 2020.
Issue or Number:1
Record Number:CaltechAUTHORS:20200109-110921859
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20200109-110921859
Official Citation:Yan Xu, Guangbin Dong, Deconstructive Functionalization of Ketones via an LMCT-Promoted C–C Cleavage, Chem, Volume 6, Issue 1, 2020, Pages 10-11, ISSN 2451-9294, https://doi.org/10.1016/j.chempr.2019.12.013. (http://www.sciencedirect.com/science/article/pii/S2451929419305601)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:100597
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:09 Jan 2020 19:33
Last Modified:09 Mar 2020 13:19

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