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Electronic structures and redox properties of boronated cyanometalates

Gray, Harry B. and McNicholas, Brendon James (2020) Electronic structures and redox properties of boronated cyanometalates. In: 259th ACS National Meeting & Exposition, 22-26 March 2020, Philadelphia, PA.

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We have synthesized and structurally characterized homoleptic and heteroleptic tris(pentafluorophenyl)borane adducts of iron, ruthenium, and osmium cyanides. The III/II formal potentials are more than 2.0 V higher in the boronated octahedral complexes; and, in the boronated heteroleptic complexes, the MLCT excited triplets are relatively long-lived (he MLCT absorptions are dramatically blue-shifted).The boronated homoleptic complexes, which are electrochem. reversible, exhibit energy efficiencies of 80% in nonaq. redox flow batteries; and the boronated heteroleptic complexes exhibit cell potentials over 3.0 V in sym-rf batteries.

Item Type:Conference or Workshop Item (Paper)
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URLURL TypeDescription Website
Gray, Harry B.0000-0002-7937-7876
McNicholas, Brendon James0000-0002-3654-681X
Additional Information:© 2020 American Chemical Society.
Record Number:CaltechAUTHORS:20200219-075302879
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:101354
Deposited By: Tony Diaz
Deposited On:19 Feb 2020 16:01
Last Modified:09 Mar 2020 13:19

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