Gray, Harry B. and McNicholas, Brendon James (2020) Electronic structures and redox properties of boronated cyanometalates. In: 259th ACS National Meeting & Exposition, 22-26 March 2020, Philadelphia, PA. https://resolver.caltech.edu/CaltechAUTHORS:20200219-075302879
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Abstract
We have synthesized and structurally characterized homoleptic and heteroleptic tris(pentafluorophenyl)borane adducts of iron, ruthenium, and osmium cyanides. The III/II formal potentials are more than 2.0 V higher in the boronated octahedral complexes; and, in the boronated heteroleptic complexes, the MLCT excited triplets are relatively long-lived (he MLCT absorptions are dramatically blue-shifted).The boronated homoleptic complexes, which are electrochem. reversible, exhibit energy efficiencies of 80% in nonaq. redox flow batteries; and the boronated heteroleptic complexes exhibit cell potentials over 3.0 V in sym-rf batteries.
| Item Type: | Conference or Workshop Item (Paper) | ||||||
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| Additional Information: | © 2020 American Chemical Society. | ||||||
| Record Number: | CaltechAUTHORS:20200219-075302879 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20200219-075302879 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 101354 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Tony Diaz | ||||||
| Deposited On: | 19 Feb 2020 16:01 | ||||||
| Last Modified: | 09 Mar 2020 13:19 |
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