Gray, Harry B. and Fajardo, Javier and Winkler, Jay Richmond (2020) Spectroscopy and photophysics of tungsten arylisocyanides. In: 259th ACS National Meeting & Exposition, 22-26 March 2020, Philadelphia, PA. https://resolver.caltech.edu/CaltechAUTHORS:20200219-101133498
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Abstract
We report the structures and spectroscopic properties of third generation tungsten(0) arylisocyanides. These complexes exhibit very intense absorptions and strikingly bright emissions in the visible region. The lowest electronic excited states, some with microsecond lifetimes, are very strong reductants. The complexes also have large two-photon absorption cross sections (> 1000 GMs), enabling the study of near-IR-triggered photoredox chem.
| Item Type: | Conference or Workshop Item (Paper) | ||||||||
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| Additional Information: | © 2020 American Chemical Society. | ||||||||
| Record Number: | CaltechAUTHORS:20200219-101133498 | ||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20200219-101133498 | ||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||
| ID Code: | 101372 | ||||||||
| Collection: | CaltechAUTHORS | ||||||||
| Deposited By: | Tony Diaz | ||||||||
| Deposited On: | 19 Feb 2020 18:16 | ||||||||
| Last Modified: | 19 Feb 2020 18:16 |
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