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Spectroscopy and photophysics of tungsten arylisocyanides

Gray, Harry B. and Fajardo, Javier and Winkler, Jay Richmond (2020) Spectroscopy and photophysics of tungsten arylisocyanides. In: 259th ACS National Meeting & Exposition, 22-26 March 2020, Philadelphia, PA.

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We report the structures and spectroscopic properties of third generation tungsten(0) arylisocyanides. These complexes exhibit very intense absorptions and strikingly bright emissions in the visible region. The lowest electronic excited states, some with microsecond lifetimes, are very strong reductants. The complexes also have large two-photon absorption cross sections (> 1000 GMs), enabling the study of near-IR-triggered photoredox chem.

Item Type:Conference or Workshop Item (Paper)
Related URLs:
URLURL TypeDescription Website
Gray, Harry B.0000-0002-7937-7876
Fajardo, Javier0000-0003-0612-7953
Winkler, Jay Richmond0000-0002-4453-9716
Additional Information:© 2020 American Chemical Society.
Record Number:CaltechAUTHORS:20200219-101133498
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:101372
Deposited By: Tony Diaz
Deposited On:19 Feb 2020 18:16
Last Modified:19 Feb 2020 18:16

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