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Ammonia emission abatement does not fully control reduced forms of nitrogen deposition

Tan, Jiani and Fu, Joshua S. and Seinfeld, John H. (2020) Ammonia emission abatement does not fully control reduced forms of nitrogen deposition. Proceedings of the National Academy of Sciences of the United States of America, 117 (18). pp. 9771-9775. ISSN 0027-8424. PMCID PMC7211968. https://resolver.caltech.edu/CaltechAUTHORS:20200420-133228103

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Abstract

Human activities and population growth have increased the natural burden of reactive nitrogen (N) in the environment. Excessive N deposition on Earth’s surface leads to adverse feedbacks on ecosystems and humans. Similar to that of air pollution, emission control is recognized as an efficient means to control acid deposition. Control of nitrogen oxides (NO_x = NO + NO₂) emissions has led to reduction in deposition of oxidized nitrogen (NO_y, the sum of all oxidized nitrogen species, except nitrous oxide [N₂O]). Reduced forms of nitrogen (NH_x = ammonia [NH₃] + ammonium [NH₄⁺]) deposition have, otherwise, increased, offsetting the benefit of reduction in NO_y deposition. Stringent control of NH₃ emissions is being considered. In this study, we assess the response of N deposition to N emission control on continental regions. We show that significant reduction of NHx deposition is unlikely to be achieved at the early stages of implementing NH₃ emission abatement. Per-unit NH₃ emission abatement is shown to result in only 60–80% reduction in NH_x deposition, which is significantly lower than the demonstrated 80–120% benefit of controlling NO_x emissions on NO_y deposition. This 60–80% effectiveness of NH_x deposition reduction per unit NH₃ emission abatement reflects, in part, the effects of simultaneous reductions in NO_x and SO₂ emissions.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1073/pnas.1920068117DOIArticle
https://www.pnas.org/content/suppl/2020/04/15/1920068117.DCSupplementalPublisherSupporting Information
http://www.ncbi.nlm.nih.gov/pmc/articles/pmc7211968/PubMed CentralArticle
ORCID:
AuthorORCID
Tan, Jiani0000-0003-3296-6339
Fu, Joshua S.0000-0001-5464-9225
Seinfeld, John H.0000-0003-1344-4068
Additional Information:© 2020 National Academy of Sciences. Published under the PNAS license. Contributed by John H. Seinfeld, February 28, 2020 (sent for review November 15, 2019; reviewed by Jeffrey Lee Collett Jr and Maria Kanakidou). PNAS first published April 20, 2020. We thank NADP and all participating modeling groups in HTAP II. We acknowledge the computational resources of the Oak Ridge National Laboratory, supported by the Office of Science of the US Department of Energy (Contract DE-AC05-00OR22725). Data Availability: All data are publicly available. Details about measurement data, emission, and modeling datasets are given in SI Appendix. Author contributions: J.T. and J.S.F. designed research; J.T. performed research; J.T. analyzed data; and J.T., J.S.F., and J.H.S. wrote the paper. Reviewers: J.L.C., Colorado State University; and M.K., University of Crete. The authors declare no competing interest. This article contains supporting information online at https://www.pnas.org/lookup/suppl/doi:10.1073/pnas.1920068117/-/DCSupplemental.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-AC05-00OR22725
Subject Keywords:nitrogen deposition; reduced forms of nitrogen; ammonia emission; emission control strategy
Issue or Number:18
PubMed Central ID:PMC7211968
Record Number:CaltechAUTHORS:20200420-133228103
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20200420-133228103
Official Citation:Ammonia emission abatement does not fully control reduced forms of nitrogen deposition. Jiani Tan, Joshua S. Fu, John H. Seinfeld. Proceedings of the National Academy of Sciences May 2020, 117 (18) 9771-9775; DOI: 10.1073/pnas.1920068117
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:102663
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:20 Apr 2020 20:52
Last Modified:02 Jun 2020 18:32

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