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Chemical kinetics of homogeneous atmospheric oxidation of sulfur dioxide

Sander, Stanley P. and Seinfeld, John H. (1976) Chemical kinetics of homogeneous atmospheric oxidation of sulfur dioxide. Environmental Science and Technology, 10 (12). pp. 1114-1123. ISSN 0013-936X. https://resolver.caltech.edu/CaltechAUTHORS:20200428-084748306

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Abstract

A systematic evaluation of known homogeneous SO₂ reactions which might be important in air pollution chemistry is carried out. A mechanism is developed to represent the chemistry of NO_x/hydrocarbon/SO₂ systems, and the mechanism is used to analyze available experimental data appropriate for quantitative analysis of SO₂ oxidation kinetics. Detailed comparisons of observed and predicted concentration behavior are presented. In all cases, observed SO₂ oxidation rates cannot be explained solely on the basis of those SO₂ reactions for which rate constants have been measured. The role of ozone-olefin reactions in SO₂ oxidation is elucidated.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1021/es60122a007DOIArticle
ORCID:
AuthorORCID
Sander, Stanley P.0000-0003-1424-3620
Seinfeld, John H.0000-0003-1344-4068
Additional Information:© 1976 American Chemical Society. Received for review January 5, 1976. Accepted April 26, 1976. Work supported in part by the Jet Propulsion Laboratory and in part by National Science Foundation Grant 71ENG-02486.
Funders:
Funding AgencyGrant Number
JPLUNSPECIFIED
NSF71ENG-02486
Issue or Number:12
Record Number:CaltechAUTHORS:20200428-084748306
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20200428-084748306
Official Citation:Chemical kinetics of homogeneous atmospheric oxidation of sulfur dioxide. Stanley P. Sander and John H. Seinfeld. Environmental Science & Technology 1976 10 (12), 1114-1123; DOI: 10.1021/es60122a007
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:102833
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:28 Apr 2020 16:13
Last Modified:28 Apr 2020 16:13

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