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Vertical Transport, Entrainment, and Scavenging Processes Affecting Trace Gases in a Modeled and Observed SEAC⁴RS Case Study

Cuchiara, G. C. and Fried, A. and Barth, M. C. and Bela, M. and Homeyer, C. R. and Gaubert, B. and Walega, J. and Weibring, P. and Richter, D. and Wennberg, P. and Crounse, J. and Kim, M. and Diskin, G. and Hanisco, T. M. and Wolfe, G. M. and Beyersdorf, A. and Peischl, J. and Pollack, I. B. and St. Clair, J. M. and Woods, S. and Tanelli, S. and Bui, T. P. and Dean‐Day, J. and Huey, G. L. and Heath, N. (2020) Vertical Transport, Entrainment, and Scavenging Processes Affecting Trace Gases in a Modeled and Observed SEAC⁴RS Case Study. Journal of Geophysical Research. Atmospheres, 125 (11). Art. No. e2019JD031957. ISSN 2169-897X. https://resolver.caltech.edu/CaltechAUTHORS:20200429-125923209

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Abstract

The convectively driven transport of soluble trace gases from the lower to the upper troposphere can occur on timescales of less than an hour, and recent studies suggest that microphysical scavenging is the dominant removal process of tropospheric ozone precursors. We examine the processes responsible for vertical transport, entrainment, and scavenging of soluble ozone precursors (formaldehyde and peroxides) for midlatitude convective storms sampled on 2 September 2013 during the Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys (SEAC⁴RS) study. Cloud‐resolving simulations using the Weather Research and Forecasting with Chemistry model combined with aircraft measurements were performed to understand the effect of entrainment, scavenging efficiency (SE), and ice physics processes on these trace gases. Analysis of the observations revealed that the SEs of formaldehyde (43–53%) and hydrogen peroxide (~80–90%) were consistent between SEAC⁴RS storms and the severe convection observed during the Deep Convective Clouds and Chemistry Experiment (DC3) campaign. However, methyl hydrogen peroxide SE was generally smaller in the SEAC⁴RS storms (4%–27%) compared to DC3 convection. Predicted ice retention factors exhibit different values for some species compared to DC3, and we attribute these differences to variations in net precipitation production. The analyses show that much larger production of precipitation between condensation and freezing levels for DC3 severe convection compared to smaller SEAC⁴RS storms is largely responsible for the lower amount of soluble gases transported to colder temperatures, reducing the amount of soluble gases which eventually interact with cloud ice particles.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1029/2019jd031957DOIArticle
ORCID:
AuthorORCID
Cuchiara, G. C.0000-0001-6094-9187
Fried, A.0000-0002-5230-3527
Barth, M. C.0000-0002-9252-0286
Bela, M.0000-0002-3998-9990
Homeyer, C. R.0000-0002-4883-6670
Gaubert, B.0000-0002-6595-0686
Walega, J.0000-0001-9167-8121
Weibring, P.0000-0001-9567-3803
Richter, D.0000-0002-2156-031X
Wennberg, P.0000-0002-6126-3854
Crounse, J.0000-0001-5443-729X
Kim, M.0000-0002-4922-4334
Diskin, G.0000-0002-3617-0269
Hanisco, T. M.0000-0001-9434-8507
Wolfe, G. M.0000-0001-6586-4043
Beyersdorf, A.0000-0002-4496-2557
Peischl, J.0000-0002-9320-7101
Pollack, I. B.0000-0001-7151-9756
St. Clair, J. M.0000-0002-9367-5749
Woods, S.0000-0003-2174-8889
Bui, T. P.0000-0001-9189-0405
Dean‐Day, J.0000-0003-2621-5774
Heath, N.0000-0003-0328-4398
Additional Information:© 2020 American Geophysical Union. Received 4 NOV 2019; Accepted 25 APR 2020; Accepted article online 29 APR 2020. We would like to thank NASA for supporting this research through grant NNX17AH52G. NCAR is sponsored by the National Science Foundation. C. Homeyer was funded by NSF grant AGS‐1522910. The authors thank Gabriele Pfister for providing additional WRF‐Chem information. The authors also thank Morgan Silverman and Gao Chen for providing SEAC⁴RS formaldehyde comparison. We also thank NASA for supporting the SEAC⁴RS campaign, the project leaders, and all the investigators for their data contributions. All data were obtained from the NASA Langley Research Center Atmospheric Science Data Center (https://www-air.larc.nasa.gov/cgi-bin/ArcView/seac4rs). We acknowledge use of the WRF‐Chem preprocessor tool (mozbc, fire_emiss, and bio_emiss) provided by the Atmospheric Chemistry Observations and Modeling Lab (ACOM) of NCAR and also the use of BOXMOX model provided by the University of Munich, Germany (http://boxmodeling.meteo.physik.uni-muenchen.de). Simone Tanelli's contributions were carried out at the Jet Propulsory Laboratory, California Institute of Technology, under a contract with the National Aeronautics and Space Administration (80NM0018D0004).
Funders:
Funding AgencyGrant Number
NASANNX17AH52G
NSFAGS-1522910
Issue or Number:11
Record Number:CaltechAUTHORS:20200429-125923209
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20200429-125923209
Official Citation:Cuchiara, G. C., Fried, A., Barth, M. C., Bela, M., Homeyer, C. R., Gaubert, B., et al. (2020). Vertical transport, entrainment, and scavenging processes affecting trace gases in a modeled and observed SEAC4RS case study. Journal of Geophysical Research: Atmospheres, 125, e2019JD031957. https://doi.org/10.1029/2019JD031957
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:102906
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:29 Apr 2020 20:38
Last Modified:12 Jun 2020 16:44

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