Wennberg, Paul and Xu, Lu and Crounse, John D. and Moller, Kristian and Kjaergaard, Henrik (2019) Unimolecular chemistry of organic peroxy radicals in the atmosphere. In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA. https://resolver.caltech.edu/CaltechAUTHORS:20200430-093519375
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Abstract
We review recent exptl. results on the unimol. chem. of org. peroxy radicals. We describe metods for measuring the rate coeffs. and products of this chem. A major focus of this work is to describing the rates and products of H-shift and endocylization reactions in substituted radicals, such as alcs., peroxides derived from alkanes, aldehydes, and biogenically-derived alkenes. We illustrate how the structure of these peroxy radicals, including their stereochem., can inhibit or accelerate the rate of this chem.
| Item Type: | Conference or Workshop Item (Paper) | ||||||||
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| Additional Information: | © 2019 American Chemical Society. | ||||||||
| Record Number: | CaltechAUTHORS:20200430-093519375 | ||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20200430-093519375 | ||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||
| ID Code: | 102917 | ||||||||
| Collection: | CaltechAUTHORS | ||||||||
| Deposited By: | Tony Diaz | ||||||||
| Deposited On: | 30 Apr 2020 18:02 | ||||||||
| Last Modified: | 30 Apr 2020 18:02 |
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