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Unimolecular chemistry of organic peroxy radicals in the atmosphere

Wennberg, Paul and Xu, Lu and Crounse, John D. and Moller, Kristian and Kjaergaard, Henrik (2019) Unimolecular chemistry of organic peroxy radicals in the atmosphere. In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA.

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We review recent exptl. results on the unimol. chem. of org. peroxy radicals. We describe metods for measuring the rate coeffs. and products of this chem. A major focus of this work is to describing the rates and products of H-shift and endocylization reactions in substituted radicals, such as alcs., peroxides derived from alkanes, aldehydes, and biogenically-derived alkenes. We illustrate how the structure of these peroxy radicals, including their stereochem., can inhibit or accelerate the rate of this chem.

Item Type:Conference or Workshop Item (Paper)
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URLURL TypeDescription Website
Wennberg, Paul0000-0002-6126-3854
Crounse, John D.0000-0001-5443-729X
Kjaergaard, Henrik0000-0002-7275-8297
Additional Information:© 2019 American Chemical Society.
Record Number:CaltechAUTHORS:20200430-093519375
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:102917
Deposited By: Tony Diaz
Deposited On:30 Apr 2020 18:02
Last Modified:30 Apr 2020 18:02

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