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Ipso-nitration of arylsilanes

Fu, Fang and Munoz, Socrates B. and Mathew, Thomas and Prakash, Surya G. K. (2019) Ipso-nitration of arylsilanes. In: 258th ACS National Meeting & Exposition, 25-29 August 2019, San Diego, CA.

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Arylsilanes stand as convenient, inexpensive and versatile reagents for org. synthesis. They enjoy the benefits of low toxicity, low cost and high chem. stability, when compared to other organometallic reagents such as organoboron, organomagnesium or organolithium compds. Furthermore, with the advent of novel, efficient C-H silylation methods, utilization of arylsilanes in synthesis warrants further exploration. Despite the extended research on nitroarenes prepn., ipso-nitration of organosilanes has thus far not been reported. Herein, we disclose a one-pot protocol for the ipsonitration of arylsilanes employing readily available reagents, under mild conditions. The scope and limitations of the present methods will be presented and efforts towards a tandem C-H silylation/nitration protocol will also be discussed.

Item Type:Conference or Workshop Item (Paper)
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Additional Information:© 2019 American Chemical Society.
Record Number:CaltechAUTHORS:20200430-094050429
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:102918
Deposited By: Tony Diaz
Deposited On:30 Apr 2020 18:01
Last Modified:30 Apr 2020 18:01

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