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Effects of uncertainties in the thermodynamic properties of aerosol components in an air quality model – Part 2: Predictions of the vapour pressures of organic compounds

Clegg, S. L. and Kleeman, M. J. and Griffin, R. J. and Seinfeld, J. H. (2008) Effects of uncertainties in the thermodynamic properties of aerosol components in an air quality model – Part 2: Predictions of the vapour pressures of organic compounds. Atmospheric Chemistry and Physics, 8 (4). pp. 1087-1103. ISSN 1680-7316. https://resolver.caltech.edu/CaltechAUTHORS:CLEacp08b

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Abstract

Air quality models that generate the concentrations of semi-volatile and other condensable organic compounds using an explicit reaction mechanism require estimates of the vapour pressures of the organic compounds that partition between the aerosol and gas phases. The model of Griffin, Kleeman and co-workers (e.g., Griffin et al., 2005) assumes that aerosol particles consist of an aqueous phase, containing inorganic electrolytes and soluble organic compounds, and a hydrophobic phase containing mainly primary hydrocarbon material. Thirty eight semi-volatile reaction products are grouped into ten surrogate species. In Part 1 of this work (Clegg et al., 2008) the thermodynamic elements of the gas/aerosol partitioning calculation are examined, and the effects of uncertainties and approximations assessed, using a simulation for the South Coast Air Basin around Los Angeles as an example. Here we compare several different methods of predicting vapour pressures of organic compounds, and use the results to determine the likely uncertainties in the vapour pressures of the semi-volatile surrogate species in the model. These are typically an order of magnitude or greater, and are further increased when the fact that each compound represents a range of reaction products (for which vapour pressures can be independently estimated) is taken into account. The effects of the vapour pressure uncertainties associated with the water-soluble semi-volatile species are determined over a wide range of atmospheric liquid water contents. The vapour pressures of the eight primary hydrocarbon surrogate species present in the model, which are normally assumed to be involatile, are also predicted. The results suggest that they have vapour pressures high enough to exist in both the aerosol and gas phases under typical atmospheric conditions.


Item Type:Article
Related URLs:
URLURL TypeDescription
http://www.atmos-chem-phys.net/8/1087/2008/OtherUNSPECIFIED
ORCID:
AuthorORCID
Seinfeld, J. H.0000-0003-1344-4068
Additional Information:© Author(s) 2008. This work is distributed under the Creative Commons Attribution 3.0 License. Received: 1 June 2007 – Published in Atmos. Chem. Phys. Discuss.: 26 July 2007. Revised: 14 December 2007 – Accepted: 28 December 2007 – Published: 27 February 2008. This research was supported by U.S. Environmental Protection Agency grant RD-831082 and Cooperative Agreement CR-831194001, by the Natural Environment Research Council of the U.K. (as a part of the Tropospheric Organic Chemistry Experiment, TORCH) and by the European Commission as part of EUCAARI (European Integrated Project on Aerosol Cloud, Climate and Air Quality Interactions). The work has not been subject to the U.S. EPA’s peer and policy review, and does not necessarily reflect the views of the Agency and no official endorsement should be inferred. The authors would like to thank the Atmospheric Sciences Modelling Division (ASMD) of U.S. EPA for hosting S.L. Clegg while carrying out this study, and P. Bhave and other ASMD members for helpful discussions.
Funders:
Funding AgencyGrant Number
Environmental Protection Agency (EPA)RD-831082
Environmental Protection Agency (EPA)CR-831194001
Natural Environment Research Council (NERC)UNSPECIFIED
European CommissionUNSPECIFIED
Issue or Number:4
Record Number:CaltechAUTHORS:CLEacp08b
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:CLEacp08b
Official Citation:Clegg, S. L., Kleeman, M. J., Griffin, R. J., and Seinfeld, J. H.: Effects of uncertainties in the thermodynamic properties of aerosol components in an air quality model – Part 2: Predictions of the vapour pressures of organic compounds, Atmos. Chem. Phys., 8, 1087-1103, 2008.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:10322
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:24 Apr 2008
Last Modified:03 Oct 2019 00:08

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