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Unexpected rise of ozone in urban and rural areas, and sulfur dioxide in rural areas during the coronavirus city lockdown in Hangzhou, China: implications for air quality

Wang, Liqiang and Li, Mengying and Yu, Shaocai and Chen, Xue and Li, Zhen and Zhang, Yibo and Jiang, Linhui and Xia, Yan and Li, Jiali and Liu, Weiping and Liu, Pengfei and Lichtfouse, Eric and Rosenfeld, Daniel and Seinfeld, John H. (2020) Unexpected rise of ozone in urban and rural areas, and sulfur dioxide in rural areas during the coronavirus city lockdown in Hangzhou, China: implications for air quality. Environmental Chemistry Letters, 18 (5). pp. 1713-1723. ISSN 1610-3653. PMCID PMC7292245. https://resolver.caltech.edu/CaltechAUTHORS:20200615-082327667

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Abstract

The outbreak of coronavirus named COVID-19, initially identified in Wuhan, China in December 2019, has spread rapidly at the global scale. Most countries have rapidly stopped almost all activities including industry, services and transportation of goods and people, thus decreasing air pollution in an unprecedented way, and providing a unique opportunity to study air pollutants. While satellite data have provided visual evidence for the global reduction in air pollution such as nitrogen dioxide (NO₂) worldwide, precise and quantitative information is missing at the local scale. Here we studied changes in particulate matter (PM_(2.5), PM₁₀), carbon monoxide (CO), NO₂, sulfur dioxide (SO₂) and ozone (O₃) at 10 urban sites in Hangzhou, a city of 7.03 million inhabitants, and at 1 rural site, before city lockdown, January 1–23, during city lockdown, January 24-February 15, and during resumption, February 16–28, in 2020. Results show that city lockdown induced a sharp decrease in PM_(2.5), PM₁₀, CO, and NO₂ concentrations at both urban and rural sites. The NO₂ decrease is explained by reduction in traffic emissions in the urban areas, and by lower regional transport in rural areas during lockdown, as expected. SO₂ concentrations decreased from 6.3 to 5.3 μg m⁻³ in the city, but increased surprisingly from 4.7 to 5.8 μg m⁻³ at the rural site: this increase is attributed both to higher coal consumption for heating and emissions from traditional fireworks of the Spring Eve and Lantern Festivals during lockdown. Unexpectedly, O₃ concentrations increased by 145% from 24.6 to 60.6 μg m⁻³ in the urban area, and from 42.0 to 62.9 μg m⁻³ in the rural area during the lockdown. This finding is explained by the weakening of chemical titration of O₃ by NO due to reductions of NO_x fresh emissions during the non-photochemical reaction period from 20:00 PM to 9:00 AM (local time). During the lockdown, compared to the same period in 2019, the daily average concentrations in the city decreased by 42.7% for PM_(2.5), 47.9% for PM₁₀, 28.6% for SO₂, 22.3% for CO and 58.4% for NO₂, which is obviously explained by the absence of city activities. Overall, we observed not only the expected reduction in some atmospheric pollutants (PM, SO₂, CO, NO₂), but also unexpected increases in SO₂ in the rural areas and of ozone (O₃) in both urban and rural areas, the latter being paradoxically due to the reduction in nitrogen oxide levels. In other words, the city lockdown has improved air quality by reducing PM_(2.5), PM₁₀, CO, and NO₂, but has also decreased air quality by augmenting O₃ and SO₂.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1007/s10311-020-01028-3DOIArticle
https://rdcu.be/b4UKiPublisherFree ReadCube access
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7292245PubMed CentralArticle
ORCID:
AuthorORCID
Yu, Shaocai0000-0001-9718-8246
Liu, Weiping0000-0002-1173-892X
Liu, Pengfei0000-0002-6714-7387
Lichtfouse, Eric0000-0002-8535-8073
Rosenfeld, Daniel0000-0002-0784-7656
Seinfeld, John H.0000-0003-1344-4068
Additional Information:© 2020 Springer Nature Switzerland AG. Received 13 May 2020; Accepted 01 June 2020; Published 12 June 2020. This work was partially supported by the Department of Science and Technology of China (Nos. 2016YFC0202702, 2018YFC0213506, and 2018YFC0213503), National Research Program for Key Issues in Air Pollution Control in China (No. DQGG0107), and National Natural Science Foundation of China (Nos. 21577126 and 41561144004). Part of this work was also supported by the “Zhejiang 1000 Talent Plan” and Research Center for Air Pollution and Health in Zhejiang University. Pengfei Li is supported by Initiation Fund for Introducing Talents of Hebei Agricultural University (412201904). Liqiang Wang and Mengying Li these authors contributed equally to this work.
Funders:
Funding AgencyGrant Number
Department of Science and Technology (China)2016YFC0202702
Department of Science and Technology (China)2018YFC0213506
Department of Science and Technology (China)2018YFC0213503
National Research Program for Key Issues in Air Pollution Control in ChinaDQGG0107
National Natural Science Foundation of China21577126
National Natural Science Foundation of China41561144004
Zhejiang 1000 Talent PlanUNSPECIFIED
Zhejiang UniversityUNSPECIFIED
Hebei Agricultural University412201904
Subject Keywords:COVID-19; Hangzhou; Lockdown; Air quality; Emission reductions; Coronavirus; PM2.5; PM10; SO2; CO; NO2; O3
Issue or Number:5
PubMed Central ID:PMC7292245
Record Number:CaltechAUTHORS:20200615-082327667
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20200615-082327667
Official Citation:Wang, L., Li, M., Yu, S. et al. Unexpected rise of ozone in urban and rural areas, and sulfur dioxide in rural areas during the coronavirus city lockdown in Hangzhou, China: implications for air quality. Environ Chem Lett 18, 1713–1723 (2020). https://doi.org/10.1007/s10311-020-01028-3
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:103905
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:15 Jun 2020 16:02
Last Modified:11 Sep 2020 17:32

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