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Sustained, Photocatalytic CO₂ Reduction to CH₄ in a Continuous Flow Reactor by Earth-Abundant Materials: Reduced Titania-Cu₂O Z-Scheme Heterostructures

Ali, Shahzad and Lee, Junho and Kim, Hwapyong and Hwang, Yunju and Razzaq, Abdul and Jung, Jin-Woo and Cho, Chang-Hee and In, Su-Il (2020) Sustained, Photocatalytic CO₂ Reduction to CH₄ in a Continuous Flow Reactor by Earth-Abundant Materials: Reduced Titania-Cu₂O Z-Scheme Heterostructures. Applied Catalysis B, 279 . Art. No. 119344. ISSN 0926-3373. https://resolver.caltech.edu/CaltechAUTHORS:20200716-145041242

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Abstract

Photocatalytic conversion of CO₂ and water vapor to hydrocarbon fuels is a promising approach for storing solar energy while reducing greenhouse gas emissions. However, still certain issues including low product yields, limited photocatalyst stability and relatively high cost have hampered practical implementation of this technology. In the present work, a unique strategy is adopted to synthesize a stable, and inexpensive photocatalyst comprised of earth-abundant materials: a reduced titania-Cu₂O Z-scheme heterostructure. Under illumination for 6 h, the optimized reduced titania-Cu₂O photocatalyst enables 0.13 % photoreduction of highly diluted CO₂ with water vapors to 462nmol g⁻¹ of CH₄ while showing excellent stability over seven testing cycles (42 h). Our studies show the Z-scheme inhibits Cu₂O photocorrosion, while its synergistic effects with reduced titania result in sustained CH₄ formation in a continuous flow photoreactor. To the best of our knowledge stability exhibited by the reduced titania-Cu₂O Z-scheme is the highest for any Cu-based photocatalyst.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1016/j.apcatb.2020.119344DOIArticle
ORCID:
AuthorORCID
Ali, Shahzad0000-0001-5904-1016
Kim, Hwapyong0000-0002-9409-8218
Hwang, Yunju0000-0002-0480-3818
Cho, Chang-Hee0000-0003-0014-5464
In, Su-Il0000-0001-9063-2041
Additional Information:© 2020 Elsevier B.V. Received 19 May 2020, Revised 4 July 2020, Accepted 15 July 2020, Available online 16 July 2020. The authors thankfully acknowledge the support of the Ministry of Science and ICT (2017R1E1A1A01074890). This research was also supported by the Technology Development Program to Solve Climate Changes of the National Research Foundation (NRF) funded by the Ministry of Science and ICT (2015M1A2A2074670) and by Flux Photon Corporation. The authors declare that there are no conflicts of interest.
Funders:
Funding AgencyGrant Number
Ministry of Science and ICT (Korea)2017R1E1A1A01074890
Ministry of Science and ICT (Korea)2015M1A2A2074670
National Research Foundation of KoreaUNSPECIFIED
Flux Photon CorporationUNSPECIFIED
Subject Keywords:Reduced titania; Oxygen vacancy; Photocatalysis; Z-scheme heterostructure; Copper oxide
Record Number:CaltechAUTHORS:20200716-145041242
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20200716-145041242
Official Citation:Shahzad Ali, Junho Lee, Hwapyong Kim, Yunju Hwang, Abdul Razzaq, Jin-Woo Jung, Chang-Hee Cho, Su-Il In, Sustained, photocatalytic CO2 reduction to CH4 in a continuous flow reactor by earth-abundant materials: Reduced titania-Cu2O Z-scheme heterostructures, Applied Catalysis B: Environmental, Volume 279, 2020, 119344, ISSN 0926-3373, https://doi.org/10.1016/j.apcatb.2020.119344. (http://www.sciencedirect.com/science/article/pii/S0926337320307591)
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:104413
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:16 Jul 2020 23:55
Last Modified:28 Jul 2020 20:11

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