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Photoluminescence properties of polynapthalenevinylene (PNV) homopolymers and block copolymers by ring–opening metathesis polymerization (ROMP) and study of their photoluminescence properties

Wagaman, M. W. and Bellmann, E. and Grubbs, R. H. (1997) Photoluminescence properties of polynapthalenevinylene (PNV) homopolymers and block copolymers by ring–opening metathesis polymerization (ROMP) and study of their photoluminescence properties. Philosophical Transactions A: Mathematical, Physical and Engineering Sciences, 355 (1725). pp. 727-734. ISSN 1364-503X. https://resolver.caltech.edu/CaltechAUTHORS:20200916-090616755

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Abstract

Well-defined transition metal catalysts have been developed over the last few years for the precise synthesis of polymers. Many of these catalysts are living and can be used to prepare near monodispersed homopolymers and block copolymers. Ring opening metathesis polymerization (ROMP) initiators have been developed that will tolerate a wide range of functionalities and reaction conditions. A family of barrelene and barrelene derivatives have been prepared which can be ROMPed to precursors to poly(phenylenevinylene) and poly(napthylenevinylene). Using newly developed techniques, these monomers are being polymerized to form block polymers that contain monomers which give homopolymers with different emission spectra. The effects of phase separation and spectral matching are being investigated.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1098/rsta.1997.0039DOIArticle
ORCID:
AuthorORCID
Grubbs, R. H.0000-0002-0057-7817
Additional Information:© 1997 The Royal Society. Discussion Meeting Issue ‘Electronics with molecular materials: from synthesis to device’ organized by D. D. C. Bradley, R. H. Friend and A. B. Holmes. We thank the Office of Naval Research and the US Air Force for financial support. We also thank J. L. Brédas and J. Cornil, who performed the calculations.
Funders:
Funding AgencyGrant Number
Office of Naval Research (ONR)UNSPECIFIED
Air Force Office of Scientific Research (AFOSR)UNSPECIFIED
Issue or Number:1725
Record Number:CaltechAUTHORS:20200916-090616755
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20200916-090616755
Official Citation:Wagaman M. W., Bellmann E. and Grubbs R. H. 1997 Photoluminescence properties of polynapthalenevinylene (PNV) homopolymers and block copolymers by ring–opening metathesis polymerization (ROMP) and study of their photoluminescence properties Phil. Trans. R. Soc. A. 355: 727–734 http://doi.org/10.1098/rsta.1997.0039
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ID Code:105404
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:16 Sep 2020 21:14
Last Modified:16 Sep 2020 21:14

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