Wagaman, M. W. and Bellmann, E. and Grubbs, R. H. (1997) Photoluminescence properties of polynapthalenevinylene (PNV) homopolymers and block copolymers by ring–opening metathesis polymerization (ROMP) and study of their photoluminescence properties. Philosophical Transactions A: Mathematical, Physical and Engineering Sciences, 355 (1725). pp. 727-734. ISSN 1364-503X. doi:10.1098/rsta.1997.0039. https://resolver.caltech.edu/CaltechAUTHORS:20200916-090616755
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Abstract
Well-defined transition metal catalysts have been developed over the last few years for the precise synthesis of polymers. Many of these catalysts are living and can be used to prepare near monodispersed homopolymers and block copolymers. Ring opening metathesis polymerization (ROMP) initiators have been developed that will tolerate a wide range of functionalities and reaction conditions. A family of barrelene and barrelene derivatives have been prepared which can be ROMPed to precursors to poly(phenylenevinylene) and poly(napthylenevinylene). Using newly developed techniques, these monomers are being polymerized to form block polymers that contain monomers which give homopolymers with different emission spectra. The effects of phase separation and spectral matching are being investigated.
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| Additional Information: | © 1997 The Royal Society. Discussion Meeting Issue ‘Electronics with molecular materials: from synthesis to device’ organized by D. D. C. Bradley, R. H. Friend and A. B. Holmes. We thank the Office of Naval Research and the US Air Force for financial support. We also thank J. L. Brédas and J. Cornil, who performed the calculations. | ||||||
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| Issue or Number: | 1725 | ||||||
| DOI: | 10.1098/rsta.1997.0039 | ||||||
| Record Number: | CaltechAUTHORS:20200916-090616755 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20200916-090616755 | ||||||
| Official Citation: | Wagaman M. W., Bellmann E. and Grubbs R. H. 1997 Photoluminescence properties of polynapthalenevinylene (PNV) homopolymers and block copolymers by ring–opening metathesis polymerization (ROMP) and study of their photoluminescence properties Phil. Trans. R. Soc. A. 355: 727–734 http://doi.org/10.1098/rsta.1997.0039 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 105404 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | George Porter | ||||||
| Deposited On: | 16 Sep 2020 21:14 | ||||||
| Last Modified: | 16 Nov 2021 18:42 |
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