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Shallow Iodine Defects Accelerate the Degradation of α-Phase Formamidinium Perovskite

Tan, Shaun and Yavuz, Ilhan and Weber, Marc H. and Huang, Tianyi and Chen, Chung-Hao and Wang, Rui and Wang, Hao-Cheng and Ko, Jeong Hoon and Nuryyeva, Selbi and Xue, Jingjing and Zhao, Yepin and Wei, Kung-Hwa and Lee, Jin-Wook and Yang, Yang (2020) Shallow Iodine Defects Accelerate the Degradation of α-Phase Formamidinium Perovskite. Joule . ISSN 2542-4351. (In Press) https://resolver.caltech.edu/CaltechAUTHORS:20200925-135425986

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Abstract

Shallow defects are mostly benign in covalent semiconductors, such as silicon, given that they do not constitute non-radiative recombination sites. In contrast, the existence of shallow defects in ionic perovskite crystals might have significant repercussions on the long-term stability of perovskite solar cells (PSCs) because of the metastability of the ubiquitous formamidinium lead triiodide (FAPbI₃) perovskite and the migration of charged point defects. Here, we show that shallow iodine interstitial defects (I_i) can be generated unintentionally during commonly used post-fabrication treatments, which can lower the cubic-to-hexagonal transformation barrier of FAPbI3-based perovskites to accelerate its phase degradation. We demonstrate that concurrently avoiding the generation of I_i and the more effective passivation of iodine vacancies (V_ī) can improve the thermodynamic stability of the films and operational stability of the PSCs. Our most stable PSC retained 92.1 % of its initial performance after nearly 1,000 h of continuous illumination operational stability testing.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1016/j.joule.2020.08.016DOIArticle
ORCID:
AuthorORCID
Yang, Yang0000-0002-4956-2034
Additional Information:© 2020 Elsevier. Received 14 June 2020, Revised 4 August 2020, Accepted 24 August 2020, Available online 23 September 2020. This work was supported by the U.S. Department of Energy’s Office of Energy Efficiency and Renewable Energy (EERE) under the Solar Energy Technologies Office under award number DE-EE0008751. Computing resources used in this work were provided by the National Center for High-Performance Computing of Turkey (UHEM) with grant number 5005902018. M.H.W. would like to acknowledge the detailed discussions with the late Kelvin G. Lynn. M.H.W.’s contributions and the PAS work was supported by subcontract to Washington State University from the University of California, Los Angeles of a grant by the U.S. Department of Energy’s Office of Energy Efficiency and Renewable Energy (EERE) under the Solar Energy Technologies Office under award number DE-EE0008751 awarded to Dr. Yang Yang. This work was also supported by the National Research Foundation of Korea (NRF) grant funded by the Korea government (MIST) under contract number NRF-2020R1F1A1067223. Author Contributions. S.T., J.-W.L., and Y.Y. conceived the idea, designed most of the experiments, analyzed all the data, and prepared the manuscript. I.Y. and S.N. performed the theoretical calculations, modeling, and analysis. M.H.W. conducted the Positron Annihilation Spectroscopy measurements and analysis. T.H. assisted in experiments and performed the X-ray photoelectron spectroscopy measurements. C.-H.C. performed the chemical synthesis, under the supervision of K.H.W. J.H.K. performed the chemical synthesis. R.W., J.X., and Y.Z. assisted with data analysis and provided helpful discussions. H.-C.W. performed the water contact angle measurements, under the supervision of K.H.W. All authors discussed and commented on the manuscript. The authors declare no competing interests.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-EE0008751
National Center for High-Performance Computing (Turkey)5005902018
National Research Foundation of KoreaNRF-2020R1F1A1067223
Subject Keywords:defects; perovskite; iodine interstitial; iodine vacancy; shallow defects; surface treatment; passivation; trifluoroacetate; formamidinium; stability
Record Number:CaltechAUTHORS:20200925-135425986
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20200925-135425986
Official Citation:Shaun Tan, Ilhan Yavuz, Marc H. Weber, Tianyi Huang, Chung-Hao Chen, Rui Wang, Hao-Cheng Wang, Jeong Hoon Ko, Selbi Nuryyeva, Jingjing Xue, Yepin Zhao, Kung-Hwa Wei, Jin-Wook Lee, Yang Yang, Shallow Iodine Defects Accelerate the Degradation of α-Phase Formamidinium Perovskite, Joule, 2020, , ISSN 2542-4351, https://doi.org/10.1016/j.joule.2020.08.016.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:105570
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:25 Sep 2020 22:53
Last Modified:25 Sep 2020 22:53

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