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Nanotechnology for catalysis and solar energy conversion

Banin, U. and Waiskopf, N and Hammarström, L. and Boschloo, G. and Freitag, M. and Johansson, E. M. J. and Sá, J. and Tian, H. and Johnston, M. B. and Herz, L. M. and Milot, R. L. and Kanatzidis, M. G. and Ke, W. and Spanopoulos, I. and Kohlstedt, K. L. and Schatz, G. C. and Lewis, N. and Meyer, T. and Nozik, A. J. and Beard, M. C. and Armstrong, F. and Megarity, C. F. and Schmuttenmaer, C. A. and Batista, V. S. and Brudvig, G. W. (2021) Nanotechnology for catalysis and solar energy conversion. Nanotechnology, 32 (4). Art. No. 042003. ISSN 0957-4484. https://resolver.caltech.edu/CaltechAUTHORS:20201106-130122089

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Abstract

This roadmap on Nanotechnology for Catalysis and Solar Energy Conversion focuses on the application of nanotechnology in addressing the current challenges of energy conversion: 'high efficiency, stability, safety, and the potential for low-cost/scalable manufacturing' to quote from the contributed article by Nathan Lewis. This roadmap focuses on solar-to-fuel conversion, solar water splitting, solar photovoltaics and bio-catalysis. It includes dye-sensitized solar cells (DSSCs), perovskite solar cells, and organic photovoltaics. Smart engineering of colloidal quantum materials and nanostructured electrodes will improve solar-to-fuel conversion efficiency, as described in the articles by Waiskopf and Banin and Meyer. Semiconductor nanoparticles will also improve solar energy conversion efficiency, as discussed by Boschloo et al in their article on DSSCs. Perovskite solar cells have advanced rapidly in recent years, including new ideas on 2D and 3D hybrid halide perovskites, as described by Spanopoulos et al 'Next generation' solar cells using multiple exciton generation (MEG) from hot carriers, described in the article by Nozik and Beard, could lead to remarkable improvement in photovoltaic efficiency by using quantization effects in semiconductor nanostructures (quantum dots, wires or wells). These challenges will not be met without simultaneous improvement in nanoscale characterization methods. Terahertz spectroscopy, discussed in the article by Milot et al is one example of a method that is overcoming the difficulties associated with nanoscale materials characterization by avoiding electrical contacts to nanoparticles, allowing characterization during device operation, and enabling characterization of a single nanoparticle. Besides experimental advances, computational science is also meeting the challenges of nanomaterials synthesis. The article by Kohlstedt and Schatz discusses the computational frameworks being used to predict structure–property relationships in materials and devices, including machine learning methods, with an emphasis on organic photovoltaics. The contribution by Megarity and Armstrong presents the 'electrochemical leaf' for improvements in electrochemistry and beyond. In addition, biohybrid approaches can take advantage of efficient and specific enzyme catalysts. These articles present the nanoscience and technology at the forefront of renewable energy development that will have significant benefits to society.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1088/1361-6528/abbce8DOIArticle
ORCID:
AuthorORCID
Banin, U.0000-0003-1698-2128
Hammarström, L.0000-0002-9933-9084
Sá, J.0000-0003-2124-9510
Tian, H.0000-0001-6897-2808
Johnston, M. B.0000-0002-0301-8033
Herz, L. M.0000-0001-9621-334X
Kanatzidis, M. G.0000-0003-2037-4168
Kohlstedt, K. L.0000-0001-8045-0930
Schatz, G. C.0000-0001-5837-4740
Lewis, N.0000-0001-5245-0538
Meyer, T.0000-0002-7006-2608
Nozik, A. J.0000-0001-7176-7645
Beard, M. C.0000-0002-2711-1355
Armstrong, F.0000-0001-8041-2491
Schmuttenmaer, C. A.0000-0001-9992-8578
Batista, V. S.0000-0002-3262-1237
Brudvig, G. W.0000-0002-7040-1892
Additional Information:© 2020 The Author(s). Published by IOP Publishing Ltd. Original content from this work may be used under the terms of the Creative Commons Attribution 4.0 licence. Any further distribution of this work must maintain attribution to the author(s) and the title of the work, journal citation and DOI. Received 11 May 2020; Revised 11 September 2020; Accepted 30 September 2020; Published 5 November 2020. This work was supported by the Israel Science Foundation (Grant No. 1867/17). U B thanks the Alfred & Erica Larisch memorial chair. This work was supported by ONR Grant N00014-20-1-2725. The authors acknowledge the support by the Center for Light Energy Activated Redox Processes (LEAP) Energy Frontier Research Center under the award DE-SC0001059. The Department of Energy, Office of Basic Energy Sciences, grant DE-FG02-03ER15483, and the Department of Energy, Office of Science, through the Joint Center for Artificial Photosynthesis, award SC-0004993, are acknowledged for support that made preparation of this manuscript possible. Support from the Solar Photochemistry program within the Division of Chemical Sciences, Geosciences, and Biosciences in the Office of Basic Energy of the Department of Energy is acknowledged. DOE funding was provided to NREL through Contract DE-AC36-086038308. C F M and F A A are supported by a grant (CF 327) from the EPA Cephalosporin Fund.
Group:JCAP
Funders:
Funding AgencyGrant Number
Israel Science Foundation1867/17
Alfred and Erica Larisch memorial chairUNSPECIFIED
Office of Naval Research (ONR)N00014-20-1-2725
Department of Energy (DOE)DE-SC0001059
Department of Energy (DOE)DE-FG02-03ER15483
Department of Energy (DOE)DE-SC0004993
Department of Energy (DOE)DE-AC36-086038308
EPA Cephalosporin FundCF 327
Issue or Number:4
Record Number:CaltechAUTHORS:20201106-130122089
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20201106-130122089
Official Citation:U Banin et al 2021 Nanotechnology 32 042003
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:106496
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:06 Nov 2020 21:20
Last Modified:06 Nov 2020 21:20

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