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Time resolved electron transfer studies between metallointercalators in DNA

Hörmann, A. and Olson, E. J. C. and Barbara, P. F. and Arkin, M. R. and Stemp, E. D. A. and Holmlin, R. E. and Barton, J. K. (1996) Time resolved electron transfer studies between metallointercalators in DNA. In: Ultrafast Phenomena X. Springer Series in Chemical Physics . No.62. Springer Berlin Heidelberg , Berlin, Heidelberg, pp. 359-360. ISBN 9783642803161. https://resolver.caltech.edu/CaltechAUTHORS:20201120-120817888

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Abstract

Ultrafast studies on the rates of DNA-mediated forward and reverse electron transfer between photoexcited [Ru(phen)₂dppz]²⁺ and various acceptors are reported. We also present the first results that resolve the ultrafast emission decay of the so-called “light-switch” molecule [Ru(phen)₂dppz]²⁺ in aqueous solution, distinguishing the diverse photophysical mechanisms of [Ru(phen)₂dppz]²⁺.


Item Type:Book Section
Related URLs:
URLURL TypeDescription
https://doi.org/10.1007/978-3-642-80314-7_157DOIArticle
https://rdcu.be/ca526PublisherFree ReadCube access
ORCID:
AuthorORCID
Stemp, E. D. A.0000-0003-2098-4214
Barton, J. K.0000-0001-9883-1600
Additional Information:© Springer-Verlag Berlin Heidelberg 1996. This work supported by the NSF and the NIH.
Funders:
Funding AgencyGrant Number
NSFUNSPECIFIED
NIHUNSPECIFIED
Subject Keywords:Electron Transfer, Kinetic Reverse, Electron Transfer, Back Electron, Transfer Solvent, Isotope Effect, Ultrafast Phenomenon
Series Name:Springer Series in Chemical Physics
Issue or Number:62
DOI:10.1007/978-3-642-80314-7_157
Record Number:CaltechAUTHORS:20201120-120817888
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20201120-120817888
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:106765
Collection:CaltechAUTHORS
Deposited By: Rebecca Minjarez
Deposited On:23 Nov 2020 17:29
Last Modified:16 Nov 2021 18:56

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