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Time resolved electron transfer studies between metallointercalators in DNA

Hörmann, A. and Olson, E. J. C. and Barbara, P. F. and Arkin, M. R. and Stemp, E. D. A. and Holmlin, R. E. and Barton, J. K. (1996) Time resolved electron transfer studies between metallointercalators in DNA. In: Ultrafast Phenomena X. Springer Series in Chemical Physics . No.62. Springer Berlin Heidelberg , Berlin, Heidelberg, pp. 359-360. ISBN 9783642803161.

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Ultrafast studies on the rates of DNA-mediated forward and reverse electron transfer between photoexcited [Ru(phen)₂dppz]²⁺ and various acceptors are reported. We also present the first results that resolve the ultrafast emission decay of the so-called “light-switch” molecule [Ru(phen)₂dppz]²⁺ in aqueous solution, distinguishing the diverse photophysical mechanisms of [Ru(phen)₂dppz]²⁺.

Item Type:Book Section
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URLURL TypeDescription ReadCube access
Stemp, E. D. A.0000-0003-2098-4214
Barton, J. K.0000-0001-9883-1600
Additional Information:© Springer-Verlag Berlin Heidelberg 1996. This work supported by the NSF and the NIH.
Funding AgencyGrant Number
Subject Keywords:Electron Transfer, Kinetic Reverse, Electron Transfer, Back Electron, Transfer Solvent, Isotope Effect, Ultrafast Phenomenon
Series Name:Springer Series in Chemical Physics
Issue or Number:62
Record Number:CaltechAUTHORS:20201120-120817888
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:106765
Deposited By: Rebecca Minjarez
Deposited On:23 Nov 2020 17:29
Last Modified:16 Nov 2021 18:56

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