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Mid-infrared radiative emission from bright hot plasmons in graphene

Kim, Laura and Kim, Seyoon and Jha, Pankaj K. and Brar, Victor W. and Atwater, Harry A. (2021) Mid-infrared radiative emission from bright hot plasmons in graphene. Nature Materials . ISSN 1476-1122. doi:10.1038/s41563-021-00935-2. (In Press) https://resolver.caltech.edu/CaltechAUTHORS:20201201-101116329

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Abstract

Carrier excitation and decay processes in graphene are of broad interest since relaxation pathways that are not present in conventional materials are enabled by a gapless Dirac electronic band structure. Here, we report that a previously unobserved decay pathway—hot plasmon emission—results in Fermi-level-dependent mid-infrared emission in graphene. Our observations of non-thermal contributions to Fermi-level-dependent radiation are an experimental demonstration of hot plasmon emission arising from a photo-inverted carrier distribution in graphene achieved via ultrafast optical excitation. Our calculations indicate that the reported plasmon emission process can be several orders of magnitude brighter than Planckian emission mechanisms in the mid-infrared spectral range. Both the use of gold nanodisks to promote scattering and localized plasmon excitation and polarization-dependent excitation measurements provide further evidence for bright hot plasmon emission. These findings define an approach for future work on ultrafast and ultrabright graphene emission processes and mid-infrared light source applications.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1038/s41563-021-00935-2DOIArticle
https://rdcu.be/ch7a9PublisherFree ReadCube access
https://arxiv.org/abs/2001.11052arXivDiscussion Paper
https://resolver.caltech.edu/CaltechTHESIS:05062019-203520662Related ItemKim (2019) Thesis
https://doi.org/10.24435/materialscloud:sa-byDOIData
ORCID:
AuthorORCID
Kim, Laura0000-0002-9745-3668
Kim, Seyoon0000-0002-8040-9521
Jha, Pankaj K.0000-0002-5839-3391
Atwater, Harry A.0000-0001-9435-0201
Additional Information:© 2021 Nature Publishing Group. Received 07 April 2020; Accepted 18 January 2021; Published 01 April 2021. This work was supported by US Department of Energy Office of Science grant no. DE-FG02-07ER46405. V.W.B. was supported by a Defense Advanced Research Projects Agency Young Faculty Award (grant no. YFA D18AP00043) and by the Gordon and Betty Moore Foundation through a Moore Inventors Fellowship. S.K. acknowledges support by a Samsung Scholarship. Parts of the text and results reported in this work have been reproduced from the thesis by L. Kim, at the California Institute of Technology, and are accessible at https://thesis.library.caltech.edu/11500/. Data availability: All measurement data are deposited in the Materials Cloud (https://doi.org/10.24435/materialscloud:sa-by), and other calculation data can be reproduced by the methods described in the Supplementary Information. These authors contributed equally: Laura Kim, Seyoon Kim. Author Contributions: L.K., V.W.B. and H.A.A. conceived the ideas. L.K. performed spectroscopy experiments, and performed inversion and gain calculations as well as emissivity calculations. L.K. and S.K. fabricated the sample and performed data analysis. P.K.J. contributed to the discussion of the ratio of stimulated to spontaneous emission rates calculations. All authors cowrote the paper. V.W.B. and H.A.A. supervised the project. The authors declare no competing interests. Peer review information: Nature Materials thanks Ortwin Hess, Frank Koppens and the other, anonymous, reviewer(s) for their contribution to the peer review of this work.
Funders:
Funding AgencyGrant Number
Department of Energy (DOE)DE-FG02-07ER46405
Defense Advanced Research Projects Agency (DARPA)YFA D18AP00043
Gordon and Betty Moore FoundationUNSPECIFIED
Samsung ScholarshipUNSPECIFIED
Subject Keywords:Nanophotonics and plasmonics; Optical properties and devices
DOI:10.1038/s41563-021-00935-2
Record Number:CaltechAUTHORS:20201201-101116329
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20201201-101116329
Official Citation:Kim, L., Kim, S., Jha, P.K. et al. Mid-infrared radiative emission from bright hot plasmons in graphene. Nat. Mater. (2021). https://doi.org/10.1038/s41563-021-00935-2
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:106857
Collection:CaltechAUTHORS
Deposited By: Tony Diaz
Deposited On:02 Dec 2020 20:07
Last Modified:05 Apr 2021 22:01

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