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Freezing point depression and freeze-thaw damage by nanofluidic salt trapping

Zhou, Tingtao and Mirzadeh, Mohammad and Pellenq, Roland J.-M. and Bazant, Martin Z. (2020) Freezing point depression and freeze-thaw damage by nanofluidic salt trapping. Physical Review Fluids, 5 (12). Art. No. 124201. ISSN 2469-990X. https://resolver.caltech.edu/CaltechAUTHORS:20201217-160839978

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Abstract

A remarkable variety of organisms and wet materials are able to endure temperatures far below the freezing point of bulk water. Cryotolerance in biology is usually attributed to “antifreeze” proteins, and yet massive supercooling (<−40∘C) is also possible in porous media containing only simple aqueous electrolytes. For concrete pavements, the common wisdom is that freeze-thaw (FT) damage results from the expansion of water upon freezing, but this cannot explain the high pressures (>10 MPa) required to damage concrete, the observed correlation between pavement damage and deicing salts, or the FT damage of cement paste loaded with benzene (which contracts upon freezing). In this work, we propose a different mechanism—nanofluidic salt trapping—which can explain the observations, using simple mathematical models of dissolved ions confined between growing ice and charged pore surfaces. When the transport time scale for ions through charged pore space is prolonged, ice formation in confined pores causes enormous disjoining pressures via the ions rejected from the ice core, until their removal by precipitation or surface adsorption at lower temperatures releases the pressure and allows complete freezing. The theory is able to predict the nonmonotonic salt-concentration dependence of FT damage in concrete and provides some hint to better understand the origins of cryotolerance from a physical chemistry perspective.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1103/physrevfluids.5.124201DOIArticle
https://arxiv.org/abs/1905.07036arXivDiscussion Paper
ORCID:
AuthorORCID
Zhou, Tingtao0000-0002-1766-719X
Mirzadeh, Mohammad0000-0003-2781-1033
Pellenq, Roland J.-M.0000-0001-5559-4190
Bazant, Martin Z.0000-0002-8200-4501
Alternate Title:Freezing point depression and freeze-thaw damage by nano-fuidic salt trapping
Additional Information:© 2020 American Physical Society. (Received 28 July 2020; accepted 9 November 2020; published 2 December 2020) The authors thank S. Yip, C. Qiao, J. Weiss, and M. Pinson for useful discussions. This work was carried out with the support of the Concrete Sustainability Hub at MIT.
Funders:
Funding AgencyGrant Number
Massachusetts Institute of Technology (MIT)UNSPECIFIED
Issue or Number:12
Record Number:CaltechAUTHORS:20201217-160839978
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20201217-160839978
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:107182
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:18 Dec 2020 15:12
Last Modified:18 Dec 2020 15:12

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