Mullins, C. B. and Wang, Y. and Weinberg, W. H. (1989) A molecular-beam study of the dissociative chemisorption of O2 on Ir(110)-(1×2). Journal of Vacuum Science and Technology A, 7 (3). pp. 2125-2126. ISSN 0734-2101. doi:10.1116/1.575985. https://resolver.caltech.edu/CaltechAUTHORS:MULjvsta89
![[img]](https://authors.library.caltech.edu/style/images/fileicons/application_pdf.png)
|
PDF
- Published Version
See Usage Policy. 242kB |
Use this Persistent URL to link to this item: https://resolver.caltech.edu/CaltechAUTHORS:MULjvsta89
Abstract
The zero-coverage probability of dissociative chemisorption of O2 on Ir(110)-(1×2) has been measured using molecular-beam techniques for a wide range of incident kinetic energies, incident angles, and surface temperatures. The data indicate that a trapping-mediated mechanism is responsible for dissociative chemisorption at low energies, whereas at high energies a direct mechanism accounts for dissociative adsorption. Total energy scaling approximately describes the dissociative dynamics on the very corrugated Ir(110)-(1×2) surface.
| Item Type: | Article | ||||||
|---|---|---|---|---|---|---|---|
| Related URLs: |
| ||||||
| ORCID: |
| ||||||
| Additional Information: | © 1989 American Vacuum Society. (Received 14 October 1988; accepted 31 October 1988) This work was supported by the National Science Foundation under Grant No. CHE-8617826. [C.B.M. was an] IBM Predoctoral Fellow. | ||||||
| Funders: |
| ||||||
| Subject Keywords: | OXYGEN; CHEMISORPTION; DISSOCIATION; MOLECULAR BEAMS; CHEMICAL REACTION KINETICS; IRIDIUM; SURFACE REACTIONS; HIGH TEMPERATURE; PROBABILITY; EXPERIMENTAL DATA; MEDIUM TEMPERATURE | ||||||
| Issue or Number: | 3 | ||||||
| DOI: | 10.1116/1.575985 | ||||||
| Record Number: | CaltechAUTHORS:MULjvsta89 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:MULjvsta89 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 10790 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Archive Administrator | ||||||
| Deposited On: | 10 Jun 2008 | ||||||
| Last Modified: | 08 Nov 2021 21:11 |
Repository Staff Only: item control page
