Bowers, C. Russell and Weitekamp, Daniel P. (1986) Transformation of Symmetrization Order to Nuclear-Spin Magnetization by Chemical Reaction and Nuclear Magnetic Resonance. Physical Review Letters, 57 (21). pp. 2645-2648. ISSN 0031-9007. doi:10.1103/PhysRevLett.57.2645. https://resolver.caltech.edu/CaltechAUTHORS:BOWprl86
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Abstract
A method of obtaining very large nuclear-spin polarizations is proposed and illustrated by density-operator calculations. The prediction is that chemical reaction and rf irradiation can convert the scalar parahydrogen state into polarization of order unity on the nuclear spins of the products of molecular-hydrogen addition reactions. A means of extending the resultant sensitivity enhancement to other spins is proposed in which the transfer of order occurs through population differences not associated with magnetization.
| Item Type: | Article | ||||||
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| Additional Information: | ©1986 The American Physical Society. Received 2 July 1986. The authors thank the Atlantic Richfield Foundation for partial support of this work. | ||||||
| Issue or Number: | 21 | ||||||
| DOI: | 10.1103/PhysRevLett.57.2645 | ||||||
| Record Number: | CaltechAUTHORS:BOWprl86 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:BOWprl86 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 10855 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | Archive Administrator | ||||||
| Deposited On: | 13 Jun 2008 | ||||||
| Last Modified: | 08 Nov 2021 21:11 |
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