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Photocatalytic production of hydrogen on Ni/NiO/KNbO_3/CdS nanocomposites using visible light

Choi, Jina and Ryu, Su Young and Balcerski, William and Lee, T. K. and Hoffmann, Michael R. (2008) Photocatalytic production of hydrogen on Ni/NiO/KNbO_3/CdS nanocomposites using visible light. Journal of Materials Chemistry, 18 (20). pp. 2371-2378. ISSN 0959-9428. https://resolver.caltech.edu/CaltechAUTHORS:CHOjmc08

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Abstract

The photocatalytic production of H2 from water splitting was demonstrated on Ni/NiO/KNbO3/CdS nanocomposites using visible light irradiation at wavelengths >400 nm in the presence of isopropanol. The inherent photocatalytic activity of bulk-phase CdS was enhanced by combining Q-sized CdS with KNbO3 and Ni deposited on KNbO3. Enhanced activity is most likely due to effective charge separation of photogenerated electrons and holes in CdS that is achieved by electron injection into the conduction band of KNbO3 and the reduced states of niobium (e.g., Nb(IV) and Nb(III)) are shown to contribute to enhanced reactivity in the KNbO3 composites by mediating effective electron transfer to bound protons. We also observed that the efficient attachment of Q-size CdS and the deposition of nickel on the KNbO3 surface increases H2 production rates. Other factors that influence the rate of H2 production including the nature of the electron donors and the solution pH were also determined. The Ni/NiO/KNbO3/CdS nanocomposite system appears to be a promising candidate for possible practical applications including the production of H2 under visible light.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1039/b718535aDOIUNSPECIFIED
ORCID:
AuthorORCID
Hoffmann, Michael R.0000-0001-6495-1946
Alternate Title:Photocatalytic production of hydrogen on Ni/NiO/KNbO3/CdS nanocomposites using visible light
Additional Information:This journal is © The Royal Society of Chemistry 2008. Received 4th December 2007, Accepted 12th March 2008. First published on the web 2nd April 2008. We are grateful to the Hydrogen Energy Research & Development Center and 21st Century Frontier Research and Development Program of the Ministry of Science and Technology of Korea for research support. This paper is part of a Journal of Materials Chemistry theme issue on hydrogen storage and generation. Guest editor: John Irvine.
Funders:
Funding AgencyGrant Number
Ministry of Science and Technology (Korea)UNSPECIFIED
Subject Keywords:DOPED TITANIUM-DIOXIDE; PHOTOCURRENT MEASUREMENTS; LOADED K4NB6O17; FILM ELECTRODES; CADMIUM-SULFIDE; ZNS-CDS; WATER; CATALYST; DECOMPOSITION; H2
Issue or Number:20
Record Number:CaltechAUTHORS:CHOjmc08
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:CHOjmc08
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:10944
Collection:CaltechAUTHORS
Deposited By: Archive Administrator
Deposited On:20 Jun 2008
Last Modified:03 Mar 2020 13:01

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