Villegas-Escobar, Nery and Martínez, Javier and Matute, Ricardo A. and Saltarini, Sebastián and Daniluc, Constantin G. and Gade, Lutz H. and Rojas, René S. (2021) Trapping an unusual pentacoordinate carbon atom in a neutral trialuminum complex. Chemical Communications, 57 (80). pp. 10327-10330. ISSN 1359-7345. doi:10.1039/d1cc04265c. https://resolver.caltech.edu/CaltechAUTHORS:20210701-165443333
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Abstract
A neutral trialuminum complex incorporates a pentacoordinate carbon through a methylidene bridge linking the three metal atoms. The rigid electron-deficient Al3 core stabilizes the hypercoordinate carbon atom resulting in the shortest equatorial Al–C distance reported for such Al₃-(µ³-CH₂) unit.
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Additional Information: | © The Royal Society of Chemistry 2021. Submitted 05 Aug 2021; Accepted 01 Sep 2021; First published 01 Sep 2021. This work was supported by FONDECYT, Project No. 1200748. N. V. E. acknowledges financial support from Fondecyt-ANID Postdoctorado Grant 3210532. J. M. acknowledges financial support from Fondecyt-ANID Postdoctorado project 3180073. R. A. M. acknowledges financial support from FONDECYT Grant 1181260. Powered@NLHPC: this research was partially supported by the supercomputing infrastructure of the NLHPC (ECM-02). This research was supported by the high-performance computing system of PIDi-UTEM (SCC-PIDi-UTEM FONDEQUIP-EQM180180). There are no conflicts to declare. | ||||||||||||||
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Subject Keywords: | pentacoordinate carbon; methylidene; trialuminium complex; DFT; bonding | ||||||||||||||
Issue or Number: | 80 | ||||||||||||||
DOI: | 10.1039/d1cc04265c | ||||||||||||||
Record Number: | CaltechAUTHORS:20210701-165443333 | ||||||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20210701-165443333 | ||||||||||||||
Official Citation: | Trapping an Unusual Pentacoordinate Carbon Atom in a Neutral Trialuminum Complex. Chem. Commun., 2021, 57, 10327-10330; DOI: 10.1039/d1cc04265c | ||||||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||||
ID Code: | 109702 | ||||||||||||||
Collection: | CaltechAUTHORS | ||||||||||||||
Deposited By: | Tony Diaz | ||||||||||||||
Deposited On: | 02 Jul 2021 19:52 | ||||||||||||||
Last Modified: | 07 Oct 2021 21:49 |
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