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Thermodynamic Properties of Phosphorus Compounds

Anderson, Thomas F. and Yost, Don M. (1936) Thermodynamic Properties of Phosphorus Compounds. Journal of Chemical Physics, 4 (8). pp. 529-530. ISSN 0021-9606. doi:10.1063/1.1749896.

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With Raman spectrum, electron diffraction and existing equilibrium data the standard virtual entropies of P(s, white), P4(g). PCl3(g), PCl3(l), PCl5(g), and PCl5(s) are calculated to be 10.55, 66.88, 74.7, 52.8, 87.7, and 40.8 cal./deg. respectively. The corresponding standard free energies of formation are calculated to be (0), 5850, —64,650, —63,570, —72,540 and —77,950 cal., respectively.

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Additional Information:Copyright © 1936 American Institute of Physics. Received June 13, 1936. Gates Chemical Laboratory, Publication No. 551
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Gates Chemical Laboratory551
Issue or Number:8
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:11203
Deposited By: Archive Administrator
Deposited On:23 Jul 2008 21:29
Last Modified:08 Nov 2021 21:34

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