Barluzzi, Luciano and Jori, Nadir and He, Tianyi and Rajeshkumar, Thayalan and Scopelliti, Rosario and Maron, Laurent and Oyala, Paul and Agapie, Theodor and Mazzanti, Marinella (2022) Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer. Chemical Communications, 58 (29). pp. 4655-4658. ISSN 1359-7345. doi:10.1039/d2cc00473a. https://resolver.caltech.edu/CaltechAUTHORS:20220323-704268000
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Abstract
The reaction of a Mo(ii) terminal nitride with U(iii) generates the first example of a transition metal capped uranium nitride. The nitride is triply bonded to U(v) and singly bonded to Mo(0) with a U–Mo interaction and reacts with CO to yield cyanate.
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| Additional Information: | © The Royal Society of Chemistry 2022. Submitted 24 Jan 2022. Accepted 10 Mar 2022. First published 10 Mar 2022. M. M. acknowledges financial support from the Swiss National Science Foundation (grant 178793) and the Ecole Polytechnique Fédérale de Lausanne (EPFL) and thanks Dr A. Sienkiewicz for preliminary EPR data collection. T. A. is grateful to the NSF for financial support (CHE-1800501). L. M. is a senior member of the Institut Universitaire de France. CalMip is acknowledged for a generous grant of computing time. There are no conflicts to declare. | ||||||||||||||||||
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| Issue or Number: | 29 | ||||||||||||||||||
| DOI: | 10.1039/d2cc00473a | ||||||||||||||||||
| Record Number: | CaltechAUTHORS:20220323-704268000 | ||||||||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20220323-704268000 | ||||||||||||||||||
| Official Citation: | Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer. Chem. Commun., 2022, 58, 4655-4658; DOI: 10.1039/d2cc00473a | ||||||||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||||||||
| ID Code: | 114023 | ||||||||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||||||||
| Deposited By: | George Porter | ||||||||||||||||||
| Deposited On: | 23 Mar 2022 21:59 | ||||||||||||||||||
| Last Modified: | 08 Apr 2022 20:50 |
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