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Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer

Barluzzi, Luciano and Jori, Nadir and He, Tianyi and Rajeshkumar, Thayalan and Scopelliti, Rosario and Maron, Laurent and Oyala, Paul and Agapie, Theodor and Mazzanti, Marinella (2022) Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer. Chemical Communications, 58 (29). pp. 4655-4658. ISSN 1359-7345. doi:10.1039/d2cc00473a. https://resolver.caltech.edu/CaltechAUTHORS:20220323-704268000

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Abstract

The reaction of a Mo(ii) terminal nitride with U(iii) generates the first example of a transition metal capped uranium nitride. The nitride is triply bonded to U(v) and singly bonded to Mo(0) with a U–Mo interaction and reacts with CO to yield cyanate.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1039/D2CC00473ADOIArticle
ORCID:
AuthorORCID
Barluzzi, Luciano0000-0001-6682-342X
Jori, Nadir0000-0002-9375-894X
He, Tianyi0000-0002-8191-188X
Scopelliti, Rosario0000-0001-8161-8715
Maron, Laurent0000-0003-2653-8557
Oyala, Paul0000-0002-8761-4667
Agapie, Theodor0000-0002-9692-7614
Mazzanti, Marinella0000-0002-3427-008X
Additional Information:© The Royal Society of Chemistry 2022. Submitted 24 Jan 2022. Accepted 10 Mar 2022. First published 10 Mar 2022. M. M. acknowledges financial support from the Swiss National Science Foundation (grant 178793) and the Ecole Polytechnique Fédérale de Lausanne (EPFL) and thanks Dr A. Sienkiewicz for preliminary EPR data collection. T. A. is grateful to the NSF for financial support (CHE-1800501). L. M. is a senior member of the Institut Universitaire de France. CalMip is acknowledged for a generous grant of computing time. There are no conflicts to declare.
Funders:
Funding AgencyGrant Number
Swiss National Science Foundation (SNSF)178793
Ecole Polytechnique Fédérale de Lausanne (EPFL)UNSPECIFIED
NSFCHE-1800501
Issue or Number:29
DOI:10.1039/d2cc00473a
Record Number:CaltechAUTHORS:20220323-704268000
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20220323-704268000
Official Citation:Heterometallic uranium/molybdenum nitride synthesis via partial N-atom transfer. Chem. Commun., 2022, 58, 4655-4658; DOI: 10.1039/d2cc00473a
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:114023
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:23 Mar 2022 21:59
Last Modified:08 Apr 2022 20:50

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