Mills, Harrison A. and Jones, Christopher G. and Anderson, Kierstyn P. and Ready, Austin D. and Djurovich, Peter I. and Khan, Saeed I. and Hohman, J. Nathan and Nelson, Hosea M. and Spokoyny, Alexander M. (2022) Sterically Invariant Carborane-Based Ligands for the Morphological and Electronic Control of Metal–Organic Chalcogenolate Assemblies. Chemistry of Materials, 34 (15). pp. 6933-6943. ISSN 0897-4756. doi:10.1021/acs.chemmater.2c01319. https://resolver.caltech.edu/CaltechAUTHORS:20220422-972321800
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Abstract
Herein, we report the use of sterically invariant carborane-based chalcogenols, containing exopolyhedral B–Se or B–S bonds, as ligands for the formation of photoluminescent copper(I)-based metal–organic chalcogenolate assemblies (MOCHAs). We show that precise tuning of the carborane dipole by changing the carborane isomer from meta to ortho allows for control over the MOCHA morphology and regulation of the resulting photophysical properties. Furthermore, microcrystal electron diffraction (MicroED) has been demonstrated as a powerful tool for metal chalcogenide structure elucidation. Through the use of MicroED, one of the isolated materials is determined to consist of zero-dimensional Cu₄(Se–C₂B₁₀H₁₁)₄ clusters with an unprecedented Cu₄Se₄ geometry.
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| Additional Information: | © 2022 American Chemical Society. Received: May 2, 2022; Revised: June 22, 2022; Published: July 18, 2022. This work was supported by NSF Grants CHE-1846849 (NSF CAREER Award to A.M.S.) and DGE-1650604. H.A.M. is a recipient of the UCLA Dissertation Year Fellowship and the M. Frederick Hawthorne Inorganic Chemistry Dissertation Award. A.M.S. thanks Dreyfus Foundation for the Camille Dreyfus Teacher Scholar Award. The authors declare no competing financial interest. Crystallographic data are available from the Cambridge Crystallographic Data Centre, under the reference number: CCDC 2121247 (A) MicroED crystallographic data for A (CIF). | ||||||||||||||||||||
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| Subject Keywords: | Diffraction, Ligands, Materials, Molecular structure, Morphology | ||||||||||||||||||||
| Issue or Number: | 15 | ||||||||||||||||||||
| DOI: | 10.1021/acs.chemmater.2c01319 | ||||||||||||||||||||
| Record Number: | CaltechAUTHORS:20220422-972321800 | ||||||||||||||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20220422-972321800 | ||||||||||||||||||||
| Official Citation: | Sterically Invariant Carborane-Based Ligands for the Morphological and Electronic Control of Metal–Organic Chalcogenolate Assemblies. Harrison A. Mills, Christopher G. Jones, Kierstyn P. Anderson, Austin D. Ready, Peter I. Djurovich, Saeed I. Khan, J. Nathan Hohman, Hosea M. Nelson, and Alexander M. Spokoyny. Chemistry of Materials 2022 34 (15), 6933-6943; DOI: 10.1021/acs.chemmater.2c01319 | ||||||||||||||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||||||||||||
| ID Code: | 114421 | ||||||||||||||||||||
| Collection: | CaltechAUTHORS | ||||||||||||||||||||
| Deposited By: | Tony Diaz | ||||||||||||||||||||
| Deposited On: | 25 Apr 2022 18:57 | ||||||||||||||||||||
| Last Modified: | 12 Aug 2022 19:44 |
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