Arca, F. and Mendez, J. P. and Ortiz, M. and Ariza, M. P. (2022) Strain-tuning of transport gaps and semiconductor-to-conductor phase transition in twinned graphene. Acta Materialia, 234 . Art. No. 117987. ISSN 1359-6454. doi:10.1016/j.actamat.2022.117987. https://resolver.caltech.edu/CaltechAUTHORS:20220513-557834000
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Abstract
We show, through the use of the Landauer-Büttiker (LB) formalism and a tight-binding (TB) model, that the transport gap of twinned graphene can be tuned through the application of a uniaxial strain in the direction normal to the twin band. Remarkably, we find that the transport gap E_(gap) bears a square-root dependence on the control parameter ϵₓ − ϵ꜀,, where ϵₓ is the applied uniaxial strain and ϵ꜀ ~ 19% is a critical strain. We interpret this dependence as evidence of criticality underlying a continuous phase transition, with ϵₓ − ϵ꜀ playing the role of control parameter and the transport gap E_(gap) playing the role of order parameter. For ϵₓ < ϵ꜀, the transport gap is non-zero and the material is semiconductor, whereas for ϵₓ > ϵ꜀ the transport gap closes to zero and the material becomes conductor, which evinces a semiconductor-to-conductor phase transition. The computed critical exponent of 1/2 places the transition in the meanfield universality class, which enables far-reaching analogies with other systems in the same class.
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Additional Information: | © 2022 The Author(s). Published by Elsevier Ltd on behalf of Acta Materialia Inc. Under a Creative Commons license. Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0). Received 24 February 2022, Revised 20 April 2022, Accepted 28 April 2022, Available online 7 May 2022, Version of Record 11 May 2022. The authors acknowledge financial support by the Consejería de Transformación Económica, Industria, Conocimiento y Universidades of Junta de Andalucía, Spain under grant number P18-RT-1485 and the Ministerio de Ciencia, Innovación y Universidades of Spain under grant number RTI2018-094325-B-I00. The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper. | ||||||||||
Group: | GALCIT | ||||||||||
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Subject Keywords: | Graphene; Geometrical twinning; Phase transformation; Critical phenomena | ||||||||||
DOI: | 10.1016/j.actamat.2022.117987 | ||||||||||
Record Number: | CaltechAUTHORS:20220513-557834000 | ||||||||||
Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20220513-557834000 | ||||||||||
Official Citation: | F. Arca, J.P. Mendez, M. Ortiz, M.P. Ariza, Strain-tuning of transport gaps and semiconductor-to-conductor phase transition in twinned graphene, Acta Materialia, Volume 234, 2022, 117987, ISSN 1359-6454, https://doi.org/10.1016/j.actamat.2022.117987. | ||||||||||
Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||||||
ID Code: | 114729 | ||||||||||
Collection: | CaltechAUTHORS | ||||||||||
Deposited By: | George Porter | ||||||||||
Deposited On: | 18 May 2022 15:18 | ||||||||||
Last Modified: | 18 May 2022 15:18 |
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