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Strain-tuning of transport gaps and semiconductor-to-conductor phase transition in twinned graphene

Arca, F. and Mendez, J. P. and Ortiz, M. and Ariza, M. P. (2022) Strain-tuning of transport gaps and semiconductor-to-conductor phase transition in twinned graphene. Acta Materialia, 234 . Art. No. 117987. ISSN 1359-6454. doi:10.1016/j.actamat.2022.117987. https://resolver.caltech.edu/CaltechAUTHORS:20220513-557834000

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Abstract

We show, through the use of the Landauer-Büttiker (LB) formalism and a tight-binding (TB) model, that the transport gap of twinned graphene can be tuned through the application of a uniaxial strain in the direction normal to the twin band. Remarkably, we find that the transport gap E_(gap) bears a square-root dependence on the control parameter ϵₓ − ϵ꜀,, where ϵₓ is the applied uniaxial strain and ϵ꜀ ~ 19% is a critical strain. We interpret this dependence as evidence of criticality underlying a continuous phase transition, with ϵₓ − ϵ꜀ playing the role of control parameter and the transport gap E_(gap) playing the role of order parameter. For ϵₓ < ϵ꜀, the transport gap is non-zero and the material is semiconductor, whereas for ϵₓ > ϵ꜀ the transport gap closes to zero and the material becomes conductor, which evinces a semiconductor-to-conductor phase transition. The computed critical exponent of 1/2 places the transition in the meanfield universality class, which enables far-reaching analogies with other systems in the same class.


Item Type:Article
Related URLs:
URLURL TypeDescription
https://doi.org/10.1016/j.actamat.2022.117987DOIArticle
https://ars.els-cdn.com/content/image/1-s2.0-S1359645422003688-mmc1.pdfPublisherSupplementary Data S1. Supplementary Raw Research Data
ORCID:
AuthorORCID
Arca, F.0000-0003-2473-4589
Mendez, J. P.0000-0002-9493-0879
Ortiz, M.0000-0001-5877-4824
Ariza, M. P.0000-0003-0266-0216
Additional Information:© 2022 The Author(s). Published by Elsevier Ltd on behalf of Acta Materialia Inc. Under a Creative Commons license. Attribution-NonCommercial-NoDerivatives 4.0 International (CC BY-NC-ND 4.0). Received 24 February 2022, Revised 20 April 2022, Accepted 28 April 2022, Available online 7 May 2022, Version of Record 11 May 2022. The authors acknowledge financial support by the Consejería de Transformación Económica, Industria, Conocimiento y Universidades of Junta de Andalucía, Spain under grant number P18-RT-1485 and the Ministerio de Ciencia, Innovación y Universidades of Spain under grant number RTI2018-094325-B-I00. The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
Group:GALCIT
Funders:
Funding AgencyGrant Number
Junta de Andalucía Consejería de Economía, Innovación, Ciencia y EmpleoP18-RT-1485
Ministerio de Ciencia, Innovación y Universidades (MCIU)RTI2018-094325-B-I00
Subject Keywords:Graphene; Geometrical twinning; Phase transformation; Critical phenomena
DOI:10.1016/j.actamat.2022.117987
Record Number:CaltechAUTHORS:20220513-557834000
Persistent URL:https://resolver.caltech.edu/CaltechAUTHORS:20220513-557834000
Official Citation:F. Arca, J.P. Mendez, M. Ortiz, M.P. Ariza, Strain-tuning of transport gaps and semiconductor-to-conductor phase transition in twinned graphene, Acta Materialia, Volume 234, 2022, 117987, ISSN 1359-6454, https://doi.org/10.1016/j.actamat.2022.117987.
Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:114729
Collection:CaltechAUTHORS
Deposited By: George Porter
Deposited On:18 May 2022 15:18
Last Modified:18 May 2022 15:18

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