Fulton, Tyler J. and Du, Yun E. and Stoltz, Brian M. (2022) Asymmetric allylic alkylation, allylation, and related reactions. In: Catalytic Asymmetric Synthesis, Fourth Edition. Wiley , New York, NY, pp. 661-704. ISBN 9781119736424. https://resolver.caltech.edu/CaltechAUTHORS:20220606-735972000
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Abstract
Transition-metal catalyzed asymmetric allylic substitution processes are powerful tactics for the enantioselective construction of a diverse scope of C-C bonds. This chapter highlights some of the most significant developments in the field of C-C bond forming asymmetric allylic substitutions from c. 2010–2020. This includes coverage of new developments in well-established Pd-catalysis, as well as the recent emergence of other metals such as Rh, Ir, and Cu. This entry endeavors to emphasize the increasing diversity and state-of-the-art in transition metal-catalyzed allylic substitutions rather than provide a comprehensive review.
| Item Type: | Book Section | ||||||
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| Additional Information: | © 2022 John Wiley & Sons. Published Online: 03 June 2022. Published Print: 03 July 2022. | ||||||
| Subject Keywords: | stereoselectivity; transition metal catalysis; substitution reactions | ||||||
| DOI: | 10.1002/9781119736424.ch17 | ||||||
| Record Number: | CaltechAUTHORS:20220606-735972000 | ||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:20220606-735972000 | ||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | ||||||
| ID Code: | 115023 | ||||||
| Collection: | CaltechAUTHORS | ||||||
| Deposited By: | George Porter | ||||||
| Deposited On: | 07 Jun 2022 15:57 | ||||||
| Last Modified: | 07 Jun 2022 15:57 |
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