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Asymmetric allylic alkylation, allylation, and related reactions

Fulton, Tyler J. and Du, Yun E. and Stoltz, Brian M. (2022) Asymmetric allylic alkylation, allylation, and related reactions. In: Catalytic Asymmetric Synthesis, Fourth Edition. Wiley , New York, NY, pp. 661-704. ISBN 9781119736424.

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Transition-metal catalyzed asymmetric allylic substitution processes are powerful tactics for the enantioselective construction of a diverse scope of C-C bonds. This chapter highlights some of the most significant developments in the field of C-C bond forming asymmetric allylic substitutions from c. 2010–2020. This includes coverage of new developments in well-established Pd-catalysis, as well as the recent emergence of other metals such as Rh, Ir, and Cu. This entry endeavors to emphasize the increasing diversity and state-of-the-art in transition metal-catalyzed allylic substitutions rather than provide a comprehensive review.

Item Type:Book Section
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URLURL TypeDescription
Fulton, Tyler J.0000-0002-9343-2456
Stoltz, Brian M.0000-0001-9837-1528
Additional Information:© 2022 John Wiley & Sons. Published Online: 03 June 2022. Published Print: 03 July 2022.
Subject Keywords:stereoselectivity; transition metal catalysis; substitution reactions
Record Number:CaltechAUTHORS:20220606-735972000
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Usage Policy:No commercial reproduction, distribution, display or performance rights in this work are provided.
ID Code:115023
Deposited By: George Porter
Deposited On:07 Jun 2022 15:57
Last Modified:07 Jun 2022 15:57

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