Felker, Peter M. and Zewail, Ahmed H. (1985) Dynamics of intramolecular vibrational-energy redistribution (IVR). II. Excess energy dependence. Journal of Chemical Physics, 82 (7). pp. 2975-2993. ISSN 0021-9606. doi:10.1063/1.448247. https://resolver.caltech.edu/CaltechAUTHORS:FELjcp85b
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Abstract
The results of picosecond-resolved measurements of intramolecular vibrational-energy redistribution (IVR) in jet-cooled anthracene at different excess energies are presented. From these results, the nature of IVR as a function of vibrational energy, the relevant time scales for the process, and the details of pertinent vibrational couplings are determined.
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| Additional Information: | © 1985 American Institute of Physics. Received 9 November 1984; accepted 17 December 1984. This work was supported by the National Science Foundation through Grant No. DMR-8105034. [P.M.F. was an] IBM Graduate Fellow. [A.H.Z. was a] Camille and Henry Dreyfus Foundation Teacher-Scholar. Arthur Amos Noyes Laboratory of Chemical Physics, Contribution No. 7117. | |||||||||
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| Subject Keywords: | ENERGY TRANSFER, VIBRATIONAL STATES, COUPLING, FLUORESCENCE, ENERGY DEPENDENCE, ANTHRACENE | |||||||||
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| Issue or Number: | 7 | |||||||||
| DOI: | 10.1063/1.448247 | |||||||||
| Record Number: | CaltechAUTHORS:FELjcp85b | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:FELjcp85b | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 11741 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Archive Administrator | |||||||||
| Deposited On: | 22 Sep 2008 20:16 | |||||||||
| Last Modified: | 08 Nov 2021 22:02 |
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