Liu, Wing-ki and Marcus, R. A. (1975) Theory of the relaxation matrix and its relation to microwave transient phenomena. II. Semiclassical calculations for systems of OCS and nonpolar collision partners. Journal of Chemical Physics, 63 (1). pp. 290-297. ISSN 0021-9606. doi:10.1063/1.431056. https://resolver.caltech.edu/CaltechAUTHORS:LIUjcp75b
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Abstract
Cross sections corresponding to relaxation times T1 and T2 measured in microwave transient experiments are calculated for systems of OCS and nonpolar collision partners, employing the recently developed semiclassical theory of molecular collisions. Cases in the presence and absence of static Stark field are described. The over-all agreement with existing experimental results is encouraging. Similarities and differences between T1/T2 values in microwave transient experiments and in molecular beam maser experiments are discussed, together with a role of semiclassical collisional selection rules.
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| Additional Information: | Copyright © 1975 American Institute of Physics. Received 16 January 1975. We have benefitted from helpful discussions with our colleagues, W. H. Flygare, J. C. McGurk, and T. G. Schmalz. Supported in part by a grant from the National Science Foundation. In partial fulfillment [by W-K.L.] of the degree of Doctor of Philosophy at the University of Illinois. | |||||||||
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| Issue or Number: | 1 | |||||||||
| DOI: | 10.1063/1.431056 | |||||||||
| Record Number: | CaltechAUTHORS:LIUjcp75b | |||||||||
| Persistent URL: | https://resolver.caltech.edu/CaltechAUTHORS:LIUjcp75b | |||||||||
| Usage Policy: | No commercial reproduction, distribution, display or performance rights in this work are provided. | |||||||||
| ID Code: | 11765 | |||||||||
| Collection: | CaltechAUTHORS | |||||||||
| Deposited By: | Archive Administrator | |||||||||
| Deposited On: | 23 Sep 2008 23:55 | |||||||||
| Last Modified: | 08 Nov 2021 22:02 |
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